Stereochemistry of formation of (2—4η)-PdCl complexes from Deuterio-substituted 1-acetyl-4-t-butylcyclohex-1-enes

W. Roy Jackson, Anna Stragalinou, Jürgen U.G. Strauss

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Abstract

The loss of and 1H 2H during the formation of (2—4η)-PdCl compounds from deuterio-substituted 1-acetyl-4-t-butylcyclohex-l-enes shows little stereoselectivity and is compatible with a mechanism of formation which involves an initial palladium-assisted enolisation of the enone.

Original languageEnglish
Pages (from-to)139-141
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1 Jan 1980

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