Stereochemistry of formation of (2—4η)-PdCl complexes from Deuterio-substituted 1-acetyl-4-t-butylcyclohex-1-enes

W. Roy Jackson; Anna Stragalinou; Jürgen U.G. Strauss

doi:10.1039/C39800000139

Stereochemistry of formation of (2—4η)-PdCl complexes from Deuterio-substituted 1-acetyl-4-t-butylcyclohex-1-enes

W. Roy Jackson, Anna Stragalinou, Jürgen U.G. Strauss

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

The loss of and ¹H ²H during the formation of (2—4η)-PdCl compounds from deuterio-substituted 1-acetyl-4-t-butylcyclohex-l-enes shows little stereoselectivity and is compatible with a mechanism of formation which involves an initial palladium-assisted enolisation of the enone.

Original language	English
Pages (from-to)	139-141
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39800000139
Publication status	Published - 1 Jan 1980

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10.1039/C39800000139

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Cite this

Jackson, W. R., Stragalinou, A., & Strauss, J. U. G. (1980). Stereochemistry of formation of (2—4η)-PdCl complexes from Deuterio-substituted 1-acetyl-4-t-butylcyclohex-1-enes. Journal of the Chemical Society, Chemical Communications, (4), 139-141. https://doi.org/10.1039/C39800000139

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abstract = "The loss of and 1H 2H during the formation of (2—4η)-PdCl compounds from deuterio-substituted 1-acetyl-4-t-butylcyclohex-l-enes shows little stereoselectivity and is compatible with a mechanism of formation which involves an initial palladium-assisted enolisation of the enone.",

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