Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)

Christine Brinkmann; Felipe García; James V. Morey; Mary McPartlin; Sanjay Singh; Andrew E.H. Wheatley; Dominic S. Wright

doi:10.1039/b700409e

Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]₂ and the unusual manganate cage [LiMn(hpp)₃]₂ (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)

Christine Brinkmann, Felipe García, James V. Morey, Mary McPartlin, Sanjay Singh, Andrew E.H. Wheatley, Dominic S. Wright

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

While the nucleophilic substitution reaction of manganocene [Cp ₂Mn] with Li(hpp) (1: 1 equivalents) gives the neutral dimer [CpMn(hpp)]₂ (1), further substitution of the Cp ligands leads to the unusual dimeric manganate cage compound [LiMn(hpp)₃]₂ (2), generated by the dimerisation of a simple tris-organomanganate monomer.

Original language	English
Pages (from-to)	1570-1572
Number of pages	3
Journal	Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/b700409e
Publication status	Published - 2007
Externally published	Yes

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10.1039/b700409e

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Brinkmann, C., García, F., Morey, J. V., McPartlin, M., Singh, S., Wheatley, A. E. H., & Wright, D. S. (2007). Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]₂ and the unusual manganate cage [LiMn(hpp)₃]₂ (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine). Dalton Transactions, (16), 1570-1572. https://doi.org/10.1039/b700409e

@article{08aa60a9122d41c3a5c06095cadd8a5a,

title = "Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)",

abstract = "While the nucleophilic substitution reaction of manganocene [Cp 2Mn] with Li(hpp) (1: 1 equivalents) gives the neutral dimer [CpMn(hpp)]2 (1), further substitution of the Cp ligands leads to the unusual dimeric manganate cage compound [LiMn(hpp)3]2 (2), generated by the dimerisation of a simple tris-organomanganate monomer.",

author = "Christine Brinkmann and Felipe Garc{\'i}a and Morey, {James V.} and Mary McPartlin and Sanjay Singh and Wheatley, {Andrew E.H.} and Wright, {Dominic S.}",

year = "2007",

doi = "10.1039/b700409e",

language = "English",

pages = "1570--1572",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "The Royal Society of Chemistry",

number = "16",

}

Brinkmann, C, García, F, Morey, JV, McPartlin, M, Singh, S, Wheatley, AEH & Wright, DS 2007, 'Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]₂ and the unusual manganate cage [LiMn(hpp)₃]₂ (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)', Dalton Transactions, no. 16, pp. 1570-1572. https://doi.org/10.1039/b700409e

Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]₂ and the unusual manganate cage [LiMn(hpp)₃]₂ (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine). / Brinkmann, Christine; García, Felipe; Morey, James V. et al.
In: Dalton Transactions, No. 16, 2007, p. 1570-1572.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)

AU - Brinkmann, Christine

AU - García, Felipe

AU - Morey, James V.

AU - McPartlin, Mary

AU - Singh, Sanjay

AU - Wheatley, Andrew E.H.

AU - Wright, Dominic S.

PY - 2007

Y1 - 2007

N2 - While the nucleophilic substitution reaction of manganocene [Cp 2Mn] with Li(hpp) (1: 1 equivalents) gives the neutral dimer [CpMn(hpp)]2 (1), further substitution of the Cp ligands leads to the unusual dimeric manganate cage compound [LiMn(hpp)3]2 (2), generated by the dimerisation of a simple tris-organomanganate monomer.

AB - While the nucleophilic substitution reaction of manganocene [Cp 2Mn] with Li(hpp) (1: 1 equivalents) gives the neutral dimer [CpMn(hpp)]2 (1), further substitution of the Cp ligands leads to the unusual dimeric manganate cage compound [LiMn(hpp)3]2 (2), generated by the dimerisation of a simple tris-organomanganate monomer.

UR - http://www.scopus.com/inward/record.url?scp=34147119041&partnerID=8YFLogxK

U2 - 10.1039/b700409e

DO - 10.1039/b700409e

M3 - Article

AN - SCOPUS:34147119041

SN - 1477-9226

SP - 1570

EP - 1572

JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)

Abstract

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Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]₂ and the unusual manganate cage [LiMn(hpp)₃]₂ (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1, 2,a]pyrimidine)