Stable Acidic Water Oxidation with a Cobalt–Iron–Lead Oxide Catalyst Operating via a Cobalt-Selective Self-Healing Mechanism

The instability and expense of anodes for water electrolyzers with acidic electrolytes can be overcome through the implementation of a cobalt-iron-lead oxide electrocatalyst, [Co–Fe–Pb]O_x, that is self-healing in the presence of dissolved metal precursors. However, the latter requirement is pernicious for the membrane and especially the cathode half-reaction since Pb²⁺ and Fe³⁺ precursors poison the state-of-the-art platinum H₂ evolving catalyst. To address this, we demonstrate the invariably stable operation of [Co–Fe–Pb]O_x in acidic solutions through a cobalt-selective self-healing mechanism without the addition of Pb²⁺ and Fe³⁺ and investigate the kinetics of the process. Soft X-ray absorption spectroscopy reveals that low concentrations of Co²⁺ in the solution stabilize the catalytically active Co(Fe) sites. The highly promising performance of this system is showcased by steady water electrooxidation at 80±1 °C and 10 mA cm⁻², using a flat electrode, at an overpotential of 0.56±0.01 V on a one-week timescale.