Spin equilibria in iron(II) hexa-amine cages

Lisandra L. Martin; Karl S. Hagen; Andreas Hauser; Raymond L. Martin; Alan M. Sargeson

doi:10.1039/C39880001313

Spin equilibria in iron(II) hexa-amine cages

Lisandra L. Martin, Karl S. Hagen, Andreas Hauser, Raymond L. Martin, Alan M. Sargeson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

41 Citations (Scopus)

Abstract

Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]²⁺ (X = Y = H, NH₂, or NH₃⁺, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin ( ⁵T_2g origin) ⇌ low-spin (¹A_1g origin) equilibria in solution, characterised by measurements of magnetism and visible and ¹H n.m.r. spectra.

Original language	English
Pages (from-to)	1313-1315
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39880001313
Publication status	Published - 1 Jan 1988

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10.1039/C39880001313

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Cite this

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title = "Spin equilibria in iron(II) hexa-amine cages",

abstract = "Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]2+ (X = Y = H, NH2, or NH3+, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin ( 5T2g origin) ⇌ low-spin (1A1g origin) equilibria in solution, characterised by measurements of magnetism and visible and 1H n.m.r. spectra.",

author = "Martin, {Lisandra L.} and Hagen, {Karl S.} and Andreas Hauser and Martin, {Raymond L.} and Sargeson, {Alan M.}",

year = "1988",

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doi = "10.1039/C39880001313",

language = "English",

pages = "1313--1315",

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TY - JOUR

T1 - Spin equilibria in iron(II) hexa-amine cages

AU - Martin, Lisandra L.

AU - Hagen, Karl S.

AU - Hauser, Andreas

AU - Martin, Raymond L.

AU - Sargeson, Alan M.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]2+ (X = Y = H, NH2, or NH3+, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin ( 5T2g origin) ⇌ low-spin (1A1g origin) equilibria in solution, characterised by measurements of magnetism and visible and 1H n.m.r. spectra.

AB - Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]2+ (X = Y = H, NH2, or NH3+, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin ( 5T2g origin) ⇌ low-spin (1A1g origin) equilibria in solution, characterised by measurements of magnetism and visible and 1H n.m.r. spectra.

UR - http://www.scopus.com/inward/record.url?scp=37049081789&partnerID=8YFLogxK

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

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