TY - JOUR
T1 - Spin equilibria in iron(II) hexa-amine cages
AU - Martin, Lisandra L.
AU - Hagen, Karl S.
AU - Hauser, Andreas
AU - Martin, Raymond L.
AU - Sargeson, Alan M.
PY - 1988/1/1
Y1 - 1988/1/1
N2 - Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]2+ (X = Y = H, NH2, or NH3+, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin ( 5T2g origin) ⇌ low-spin (1A1g origin) equilibria in solution, characterised by measurements of magnetism and visible and 1H n.m.r. spectra.
AB - Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]2+ (X = Y = H, NH2, or NH3+, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin ( 5T2g origin) ⇌ low-spin (1A1g origin) equilibria in solution, characterised by measurements of magnetism and visible and 1H n.m.r. spectra.
UR - http://www.scopus.com/inward/record.url?scp=37049081789&partnerID=8YFLogxK
U2 - 10.1039/C39880001313
DO - 10.1039/C39880001313
M3 - Article
AN - SCOPUS:37049081789
SP - 1313
EP - 1315
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 19
ER -