Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3) with a rare (10,3)-d net

Jinyu Sun; Yaming Zhou; Zhenxia Chen; Guangshan Zhu; Qianrong Fang; Rongjing Yang; Shilun Qiu; Dongyuan Zhao

doi:10.1016/j.jssc.2006.01.039

Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO₃) with a rare (10,3)-d net

Jinyu Sun
, Yaming Zhou
, Zhenxia Chen
, Guangshan Zhu
, Qianrong Fang
, Rongjing Yang
, Shilun Qiu
, Dongyuan Zhao

Research output: Contribution to journal › Article › Research › peer-review

8 Citations (Scopus)

Abstract

A basic zinc nitrate, [Zn(OH)(NO₃)]_n with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna2₁ (No. 33), a=9.148(3)Å, b=7.596(3)Å, c=5.500(2)Å, Z=4, V=382.2(2)Å3, ρcalcd=2.509Mg/m3, μ=6.290mm-1, 3.49<θ<27.51, T=293K, R1=0.029, wR2=0.0773 for 697 (I>2σ(I)) of 1728 [R(int)=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO₃)]_n behaves well at removal capacity for hydrogen chloride gas, 20.3 g HCl/100 g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment.

Original language	English
Pages (from-to)	1230-1236
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	179
Issue number	4
DOIs	https://doi.org/10.1016/j.jssc.2006.01.039
Publication status	Published - 1 Jan 2006
Externally published	Yes

Keywords

Adsorption
Crystal structure
Polymorphism
Zeotype analogue
Zn

Access to Document

10.1016/j.jssc.2006.01.039

Cite this

@article{5e1613de19da4863a2b792d06e4bc727,

title = "Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3) with a rare (10,3)-d net",

abstract = "A basic zinc nitrate, [Zn(OH)(NO3)]n with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna21 (No. 33), a=9.148(3){\AA}, b=7.596(3){\AA}, c=5.500(2){\AA}, Z=4, V=382.2(2){\AA}3, ρcalcd=2.509Mg/m3, μ=6.290mm-1, 3.49<θ<27.51, T=293K, R1=0.029, wR2=0.0773 for 697 (I>2σ(I)) of 1728 [R(int)=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO3)]n behaves well at removal capacity for hydrogen chloride gas, 20.3 g HCl/100 g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment.",

keywords = "Adsorption, Crystal structure, Polymorphism, Zeotype analogue, Zn",

author = "Jinyu Sun and Yaming Zhou and Zhenxia Chen and Guangshan Zhu and Qianrong Fang and Rongjing Yang and Shilun Qiu and Dongyuan Zhao",

year = "2006",

month = jan,

day = "1",

doi = "10.1016/j.jssc.2006.01.039",

language = "English",

volume = "179",

pages = "1230--1236",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Elsevier BV",

number = "4",

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TY - JOUR

T1 - Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3) with a rare (10,3)-d net

AU - Sun, Jinyu

AU - Zhou, Yaming

AU - Chen, Zhenxia

AU - Zhu, Guangshan

AU - Fang, Qianrong

AU - Yang, Rongjing

AU - Qiu, Shilun

AU - Zhao, Dongyuan

PY - 2006/1/1

Y1 - 2006/1/1

N2 - A basic zinc nitrate, [Zn(OH)(NO3)]n with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna21 (No. 33), a=9.148(3)Å, b=7.596(3)Å, c=5.500(2)Å, Z=4, V=382.2(2)Å3, ρcalcd=2.509Mg/m3, μ=6.290mm-1, 3.49<θ<27.51, T=293K, R1=0.029, wR2=0.0773 for 697 (I>2σ(I)) of 1728 [R(int)=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO3)]n behaves well at removal capacity for hydrogen chloride gas, 20.3 g HCl/100 g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment.

AB - A basic zinc nitrate, [Zn(OH)(NO3)]n with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna21 (No. 33), a=9.148(3)Å, b=7.596(3)Å, c=5.500(2)Å, Z=4, V=382.2(2)Å3, ρcalcd=2.509Mg/m3, μ=6.290mm-1, 3.49<θ<27.51, T=293K, R1=0.029, wR2=0.0773 for 697 (I>2σ(I)) of 1728 [R(int)=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO3)]n behaves well at removal capacity for hydrogen chloride gas, 20.3 g HCl/100 g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment.

KW - Adsorption

KW - Crystal structure

KW - Polymorphism

KW - Zeotype analogue

KW - Zn

UR - https://www.scopus.com/pages/publications/33644945192

U2 - 10.1016/j.jssc.2006.01.039

DO - 10.1016/j.jssc.2006.01.039

M3 - Article

AN - SCOPUS:33644945192

SN - 0022-4596

VL - 179

SP - 1230

EP - 1236

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 4