Solid source growth of graphene with Ni-Cu catalysts: towards high quality in situ graphene on silicon

Neeraj Mishra, John J. Boeckl, Anton Tadich, Robert T Jones, Paul J Pigram, Mark Edmonds, Michael S. Fuhrer, Barbara M. Nichols, Francesca Iacopi

Research output: Contribution to journalArticleResearchpeer-review

Abstract

We obtain a monolayer graphene on epitaxial silicon carbide on silicon substrates via solid source growth mediated by a thin Ni-Cu alloy. Raman spectroscopy consistently shows an ID/IG band ratio as low as ∼0.2, indicating that the graphene obtained through this method is to-date the best quality monolayer grown on epitaxial silicon carbide films on silicon. We describe the key steps behind the graphene synthesis on the basis of extensive physical, chemical and morphological analyses. We conclude that (1) the oxidation, amorphisation and silicidation of the silicon carbide surface mediated by the Ni, (2) the liquid-phase epitaxial growth of graphene as well as (3) the self-limiting graphitization provided the molten Cu catalyst, are key characteristics of this novel synthesis method.

Original languageEnglish
Article number095302
Number of pages9
JournalJournal of Physics D: Applied Physics
Volume50
Issue number9
DOIs
Publication statusPublished - 1 Feb 2017

Keywords

  • 3C-SiC
  • graphene
  • liquid phase growth
  • silicon
  • soft x-rays

Cite this

Mishra, Neeraj ; Boeckl, John J. ; Tadich, Anton ; Jones, Robert T ; Pigram, Paul J ; Edmonds, Mark ; Fuhrer, Michael S. ; Nichols, Barbara M. ; Iacopi, Francesca. / Solid source growth of graphene with Ni-Cu catalysts : towards high quality in situ graphene on silicon. In: Journal of Physics D: Applied Physics. 2017 ; Vol. 50, No. 9.
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Solid source growth of graphene with Ni-Cu catalysts : towards high quality in situ graphene on silicon. / Mishra, Neeraj; Boeckl, John J.; Tadich, Anton; Jones, Robert T; Pigram, Paul J; Edmonds, Mark; Fuhrer, Michael S.; Nichols, Barbara M.; Iacopi, Francesca.

In: Journal of Physics D: Applied Physics, Vol. 50, No. 9, 095302, 01.02.2017.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Solid source growth of graphene with Ni-Cu catalysts

T2 - towards high quality in situ graphene on silicon

AU - Mishra, Neeraj

AU - Boeckl, John J.

AU - Tadich, Anton

AU - Jones, Robert T

AU - Pigram, Paul J

AU - Edmonds, Mark

AU - Fuhrer, Michael S.

AU - Nichols, Barbara M.

AU - Iacopi, Francesca

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AB - We obtain a monolayer graphene on epitaxial silicon carbide on silicon substrates via solid source growth mediated by a thin Ni-Cu alloy. Raman spectroscopy consistently shows an ID/IG band ratio as low as ∼0.2, indicating that the graphene obtained through this method is to-date the best quality monolayer grown on epitaxial silicon carbide films on silicon. We describe the key steps behind the graphene synthesis on the basis of extensive physical, chemical and morphological analyses. We conclude that (1) the oxidation, amorphisation and silicidation of the silicon carbide surface mediated by the Ni, (2) the liquid-phase epitaxial growth of graphene as well as (3) the self-limiting graphitization provided the molten Cu catalyst, are key characteristics of this novel synthesis method.

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