Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- tBu)Zn( tBu)] towards TEMPO and chalcone

D. R. Armstrong; L. Balloch; J. J. Crawford; B. J. Fleming; L. M. Hogg; A. R. Kennedy; J. Klett; R. E. Mulvey; Charles T. O'Hara; S. A. Orr; S. D. Robertson

doi:10.1039/c1cc12869h

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- ^tBu)Zn( ^tBu)] towards TEMPO and chalcone

D. R. Armstrong, L. Balloch, J. J. Crawford, B. J. Fleming, L. M. Hogg, A. R. Kennedy, J. Klett, R. E. Mulvey, Charles T. O'Hara, S. A. Orr, S. D. Robertson

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

More usually thought of as a base, the sodium zincate [(TMEDA) ·Na(μ-TMP)(μ- ^tBu)Zn( ^tBu)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)·Na(μ-TMP)(μ- TEMPO ^-)Zn( ^tBu)] 2 and [(TMEDA)·Na(μ-TEMPO ^-) ₂Zn( ^tBu)] 3; and with chalcone [PhCOCHCHPh] gives [{(TMEDA)·Na(μ-TMP)Zn( ^tBu)} ₂(μ- OCPhCHCHPhCHPhCHCPh-μ-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

Original language	English
Pages (from-to)	1541-1543
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc12869h
Publication status	Published - 1 Feb 2012
Externally published	Yes

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10.1039/c1cc12869h

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Armstrong, D. R., Balloch, L., Crawford, J. J., Fleming, B. J., Hogg, L. M., Kennedy, A. R., Klett, J., Mulvey, R. E., O'Hara, C. T., Orr, S. A., & Robertson, S. D. (2012). Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- ^tBu)Zn( ^tBu)] towards TEMPO and chalcone. Chemical Communications, 48(10), 1541-1543. https://doi.org/10.1039/c1cc12869h

Armstrong, D. R. ; Balloch, L. ; Crawford, J. J. ; Fleming, B. J. ; Hogg, L. M. ; Kennedy, A. R. ; Klett, J. ; Mulvey, R. E. ; O'Hara, Charles T. ; Orr, S. A. ; Robertson, S. D. / Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- ^tBu)Zn( ^tBu)] towards TEMPO and chalcone. In: Chemical Communications. 2012 ; Vol. 48, No. 10. pp. 1541-1543.

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title = "Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- tBu)Zn( tBu)] towards TEMPO and chalcone",

abstract = "More usually thought of as a base, the sodium zincate [(TMEDA) ·Na(μ-TMP)(μ- tBu)Zn( tBu)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)·Na(μ-TMP)(μ- TEMPO -)Zn( tBu)] 2 and [(TMEDA)·Na(μ-TEMPO -) 2Zn( tBu)] 3; and with chalcone [PhCOCHCHPh] gives [{(TMEDA)·Na(μ-TMP)Zn( tBu)} 2(μ- OCPhCHCHPhCHPhCHCPh-μ-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.",

author = "Armstrong, {D. R.} and L. Balloch and Crawford, {J. J.} and Fleming, {B. J.} and Hogg, {L. M.} and Kennedy, {A. R.} and J. Klett and Mulvey, {R. E.} and O'Hara, {Charles T.} and Orr, {S. A.} and Robertson, {S. D.}",

year = "2012",

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day = "1",

doi = "10.1039/c1cc12869h",

language = "English",

volume = "48",

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Armstrong, DR, Balloch, L, Crawford, JJ, Fleming, BJ, Hogg, LM, Kennedy, AR, Klett, J, Mulvey, RE, O'Hara, CT, Orr, SA & Robertson, SD 2012, 'Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- ^tBu)Zn( ^tBu)] towards TEMPO and chalcone', Chemical Communications, vol. 48, no. 10, pp. 1541-1543. https://doi.org/10.1039/c1cc12869h

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- ^tBu)Zn( ^tBu)] towards TEMPO and chalcone. / Armstrong, D. R.; Balloch, L.; Crawford, J. J.; Fleming, B. J.; Hogg, L. M.; Kennedy, A. R.; Klett, J.; Mulvey, R. E.; O'Hara, Charles T.; Orr, S. A.; Robertson, S. D.

In: Chemical Communications, Vol. 48, No. 10, 01.02.2012, p. 1541-1543.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ- tBu)Zn( tBu)] towards TEMPO and chalcone

AU - Armstrong, D. R.

AU - Balloch, L.

AU - Crawford, J. J.

AU - Fleming, B. J.

AU - Hogg, L. M.

AU - Kennedy, A. R.

AU - Klett, J.

AU - Mulvey, R. E.

AU - O'Hara, Charles T.

AU - Orr, S. A.

AU - Robertson, S. D.

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AB - More usually thought of as a base, the sodium zincate [(TMEDA) ·Na(μ-TMP)(μ- tBu)Zn( tBu)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)·Na(μ-TMP)(μ- TEMPO -)Zn( tBu)] 2 and [(TMEDA)·Na(μ-TEMPO -) 2Zn( tBu)] 3; and with chalcone [PhCOCHCHPh] gives [{(TMEDA)·Na(μ-TMP)Zn( tBu)} 2(μ- OCPhCHCHPhCHPhCHCPh-μ-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

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