Simplifying metal-'ate' chemistry

formation and comprehensive characterisation of a homo-metallic amido lithiate complex

Research output: Contribution to journalArticleResearchpeer-review

4 Citations (Scopus)

Abstract

Addition of TMEDA to lithium allyl-1-naphthylamide in a 1 : 1 ratio afforded the novel amido lithium/lithiate complex, [Li(TMEDA)2][Li{N(1-naph)(CH2CHCH2)}2]. 7Li NMR and computational calculations indicate this model to be representative of the solution state, with 1H and 13C NMR showing a 1,3-sigmatropic rearrangement. [Li{N(1-naph)(CH2CHCH2)}·Et2O]21, and [Li{N(1-naph) (CH2CHCH2)}·PMDETA] 3, are presented for comparison.

Original languageEnglish
Pages (from-to)10887-10890
Number of pages4
JournalDalton Transactions
Volume45
Issue number27
DOIs
Publication statusPublished - 21 Jul 2016

Cite this

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title = "Simplifying metal-'ate' chemistry: formation and comprehensive characterisation of a homo-metallic amido lithiate complex",
abstract = "Addition of TMEDA to lithium allyl-1-naphthylamide in a 1 : 1 ratio afforded the novel amido lithium/lithiate complex, [Li(TMEDA)2][Li{N(1-naph)(CH2CHCH2)}2]. 7Li NMR and computational calculations indicate this model to be representative of the solution state, with 1H and 13C NMR showing a 1,3-sigmatropic rearrangement. [Li{N(1-naph)(CH2CHCH2)}·Et2O]21, and [Li{N(1-naph) (CH2CHCH2)}·PMDETA] 3, are presented for comparison.",
author = "Greer, {Jamie A.} and Blair, {Victoria L.} and Thompson, {Christopher D.} and Andrews, {Philip C.}",
year = "2016",
month = "7",
day = "21",
doi = "10.1039/c6dt01630h",
language = "English",
volume = "45",
pages = "10887--10890",
journal = "Journal of the Chemical Society. Dalton Transactions",
issn = "1477-9226",
publisher = "The Royal Society of Chemistry",
number = "27",

}

Simplifying metal-'ate' chemistry : formation and comprehensive characterisation of a homo-metallic amido lithiate complex. / Greer, Jamie A.; Blair, Victoria L.; Thompson, Christopher D.; Andrews, Philip C.

In: Dalton Transactions, Vol. 45, No. 27, 21.07.2016, p. 10887-10890.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Simplifying metal-'ate' chemistry

T2 - formation and comprehensive characterisation of a homo-metallic amido lithiate complex

AU - Greer, Jamie A.

AU - Blair, Victoria L.

AU - Thompson, Christopher D.

AU - Andrews, Philip C.

PY - 2016/7/21

Y1 - 2016/7/21

N2 - Addition of TMEDA to lithium allyl-1-naphthylamide in a 1 : 1 ratio afforded the novel amido lithium/lithiate complex, [Li(TMEDA)2][Li{N(1-naph)(CH2CHCH2)}2]. 7Li NMR and computational calculations indicate this model to be representative of the solution state, with 1H and 13C NMR showing a 1,3-sigmatropic rearrangement. [Li{N(1-naph)(CH2CHCH2)}·Et2O]21, and [Li{N(1-naph) (CH2CHCH2)}·PMDETA] 3, are presented for comparison.

AB - Addition of TMEDA to lithium allyl-1-naphthylamide in a 1 : 1 ratio afforded the novel amido lithium/lithiate complex, [Li(TMEDA)2][Li{N(1-naph)(CH2CHCH2)}2]. 7Li NMR and computational calculations indicate this model to be representative of the solution state, with 1H and 13C NMR showing a 1,3-sigmatropic rearrangement. [Li{N(1-naph)(CH2CHCH2)}·Et2O]21, and [Li{N(1-naph) (CH2CHCH2)}·PMDETA] 3, are presented for comparison.

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UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2016/dt/c6dt01630h

U2 - 10.1039/c6dt01630h

DO - 10.1039/c6dt01630h

M3 - Article

VL - 45

SP - 10887

EP - 10890

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

SN - 1477-9226

IS - 27

ER -