Simple homopolymer-incarcerated gold nanoclusters prepared by self-assembled encapsulation with aluminum reagents as crosslinkers: Catalysts for aerobic oxidation reactions

Tomohiro Yasukawa, Hiroyuki Miyamura, Shu Kobayashi

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2 Citations (Scopus)

Abstract

Simple homopolymer-incarcerated gold nanocluster catalysts were developed using a self-assembled encapsulation strategy. In this method, Red-Al® acting as a reductant also played the role of an inter-crosslinker via the formation of tetraalkoxyaluminate with the hydroxy groups in a homopolymer. Gold nanoclusters could be immobilized at high loadings without aggregation, and high catalytic activities were observed in several aerobic oxidation reactions.

Original languageEnglish
Pages (from-to)50-52
Number of pages3
JournalChemistry Letters
Volume44
Issue number1
DOIs
Publication statusPublished - Jan 2015
Externally publishedYes

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