Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality

Stephanie Boer, David Roger Turner

Research output: Contribution to journalArticleOtherpeer-review

Abstract

Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.
Original languageEnglish
Pages (from-to)17375-17378
Number of pages4
JournalChemical Communications
Volume51
Issue number98
DOIs
Publication statusPublished - 2015

Cite this

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title = "Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality",
abstract = "Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.",
author = "Stephanie Boer and Turner, {David Roger}",
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language = "English",
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Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality. / Boer, Stephanie; Turner, David Roger.

In: Chemical Communications, Vol. 51, No. 98, 2015, p. 17375-17378.

Research output: Contribution to journalArticleOtherpeer-review

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AB - Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.

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