Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality

Stephanie Boer; David Roger Turner

doi:10.1039/c5cc07422c

Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality

Stephanie Boer, David Roger Turner

School of Chemistry

Research output: Contribution to journal › Article › Other › peer-review

35 Citations (Scopus)

Abstract

Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.

Original language	English
Pages (from-to)	17375-17378
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	98
DOIs	https://doi.org/10.1039/c5cc07422c
Publication status	Published - 2015

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10.1039/c5cc07422c

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title = "Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality",

abstract = "Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet {\textquoteleft}turns off{\textquoteright} the supramolecular chirality by producing centrosymmetric cages.",

author = "Stephanie Boer and Turner, {David Roger}",

year = "2015",

doi = "10.1039/c5cc07422c",

language = "English",

volume = "51",

pages = "17375--17378",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

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T1 - Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality

AU - Boer, Stephanie

AU - Turner, David Roger

PY - 2015

Y1 - 2015

N2 - Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.

AB - Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2015/cc/c5cc07422c

U2 - 10.1039/c5cc07422c

DO - 10.1039/c5cc07422c

M3 - Article

SN - 1359-7345

VL - 51

SP - 17375

EP - 17378

JO - Chemical Communications

JF - Chemical Communications

IS - 98

ER -

Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality

Abstract

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Functional Supramolecular Materials for Sensing and Sequestration

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Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality

Abstract

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Functional Supramolecular Materials for Sensing and Sequestration

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