Self-assembled, optically-active {naphthalene diimide}U{cucurbit[8]uril} ensembles in an aqueous environment

Heather F. Higginbotham, Subashani Maniam, Tina Hsia, Lyle Isaacs, Steven J. Langford, Toby D.M. Bell

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Naphthalene diimides (NDIs) are shown to arrange spontaneously co-facially with cucurbit[8]uril (CB[8]) in an aqueous environment through purely non-covalent interactions. The resultant 2 : 2 supramolecular complex of NDI and CB[8] is highly fluorescent (>30 times more than the constituent NDIs) due to the formation of NDI-NDI excimers within the supramolecular complex.

Original languageEnglish
Pages (from-to)13434-13439
Number of pages6
JournalPhysical Chemistry Chemical Physics
Volume23
Issue number24
DOIs
Publication statusPublished - 22 Jun 2021

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