Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Angus C.G. Shephard; Daisy P. Daniels; Glen B. Deacon; Zhifang Guo; Florian Jaroschik; Peter C. Junk

doi:10.1039/d2cc00698g

Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Angus C.G. Shephard, Daisy P. Daniels, Glen B. Deacon, Zhifang Guo, Florian Jaroschik, Peter C. Junk

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C-P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.

Original language	English
Pages (from-to)	4344-4347
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	27
DOIs	https://doi.org/10.1039/d2cc00698g
Publication status	Published - 7 Apr 2022

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10.1039/d2cc00698g

Cite this

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abstract = "The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C-P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.",

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AU - Guo, Zhifang

AU - Jaroschik, Florian

AU - Junk, Peter C.

PY - 2022/4/7

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AB - The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C-P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Abstract

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Other files and links

CTREC: Challenging targets in rare earth metal-organic chemistry

Australian Synchrotron

Cite this

Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Abstract

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Projects

CTREC: Challenging targets in rare earth metal-organic chemistry

Equipment

Australian Synchrotron

Cite this