TY - JOUR
T1 - S -> N type Smiles rearrangement of the aminoethanethiol moiety attached to heterocyclic compounds
AU - Mountford, Simon John
AU - Campi, Eva Mary
AU - Robinson, Andrea Jane
AU - Hearn, Milton Thomas William
PY - 2010
Y1 - 2010
N2 - Base catalysed S -> N type Smiles rearrangement of aminoethanethiol-substituted pyridine and triazine compounds led to formation of the corresponding thiol or disulfide compounds. Prior to rearrangement, the heteroaryl sulfanylethylamines could be prepared in high yields as the hydrochloride or trifluoroacetate salts from the corresponding tert-BOC protected amine. (C) 2010 Elsevier Ltd. All rights reserved.
AB - Base catalysed S -> N type Smiles rearrangement of aminoethanethiol-substituted pyridine and triazine compounds led to formation of the corresponding thiol or disulfide compounds. Prior to rearrangement, the heteroaryl sulfanylethylamines could be prepared in high yields as the hydrochloride or trifluoroacetate salts from the corresponding tert-BOC protected amine. (C) 2010 Elsevier Ltd. All rights reserved.
UR - http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THR-4YKGJ1D-7&_user=542840&_coverDate=05%2F08%2F2010&_rdoc=1&_fmt=high&_orig=search&_origin
U2 - 10.1016/j.tet.2010.03.027
DO - 10.1016/j.tet.2010.03.027
M3 - Article
SN - 0040-4020
VL - 66
SP - 3452
EP - 3456
JO - Tetrahedron
JF - Tetrahedron
IS - 19
ER -