Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces

Dorna Esrafilzadeh, Ali Zavabeti, Rouhollah Jalili, Paul Atkin, Jay Choi, Benjamin J. Carey, Robert Brkljača, Anthony P. O’Mullane, Michael D. Dickey, David L. Officer, Douglas R. MacFarlane, Torben Daeneke, Kourosh Kalantar-Zadeh

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Abstract

Negative carbon emission technologies are critical for ensuring a future stable climate. However, the gaseous state of CO 2 does render the indefinite storage of this greenhouse gas challenging. Herein, we created a liquid metal electrocatalyst that contains metallic elemental cerium nanoparticles, which facilitates the electrochemical reduction of CO 2 to layered solid carbonaceous species, at a low onset potential of −310 mV vs CO 2 /C. We exploited the formation of a cerium oxide catalyst at the liquid metal/electrolyte interface, which together with cerium nanoparticles, promoted the room temperature reduction of CO 2 . Due to the inhibition of van der Waals adhesion at the liquid interface, the electrode was remarkably resistant to deactivation via coking caused by solid carbonaceous species. The as-produced solid carbonaceous materials could be utilised for the fabrication of high-performance capacitor electrodes. Overall, this liquid metal enabled electrocatalytic process at room temperature may result in a viable negative emission technology.

Original languageEnglish
Article number865
Number of pages8
JournalNature Communications
Volume10
Issue number1
DOIs
Publication statusPublished - 1 Dec 2019

Cite this

Esrafilzadeh, Dorna ; Zavabeti, Ali ; Jalili, Rouhollah ; Atkin, Paul ; Choi, Jay ; Carey, Benjamin J. ; Brkljača, Robert ; O’Mullane, Anthony P. ; Dickey, Michael D. ; Officer, David L. ; MacFarlane, Douglas R. ; Daeneke, Torben ; Kalantar-Zadeh, Kourosh. / Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces. In: Nature Communications. 2019 ; Vol. 10, No. 1.
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abstract = "Negative carbon emission technologies are critical for ensuring a future stable climate. However, the gaseous state of CO 2 does render the indefinite storage of this greenhouse gas challenging. Herein, we created a liquid metal electrocatalyst that contains metallic elemental cerium nanoparticles, which facilitates the electrochemical reduction of CO 2 to layered solid carbonaceous species, at a low onset potential of −310 mV vs CO 2 /C. We exploited the formation of a cerium oxide catalyst at the liquid metal/electrolyte interface, which together with cerium nanoparticles, promoted the room temperature reduction of CO 2 . Due to the inhibition of van der Waals adhesion at the liquid interface, the electrode was remarkably resistant to deactivation via coking caused by solid carbonaceous species. The as-produced solid carbonaceous materials could be utilised for the fabrication of high-performance capacitor electrodes. Overall, this liquid metal enabled electrocatalytic process at room temperature may result in a viable negative emission technology.",
author = "Dorna Esrafilzadeh and Ali Zavabeti and Rouhollah Jalili and Paul Atkin and Jay Choi and Carey, {Benjamin J.} and Robert Brkljača and O’Mullane, {Anthony P.} and Dickey, {Michael D.} and Officer, {David L.} and MacFarlane, {Douglas R.} and Torben Daeneke and Kourosh Kalantar-Zadeh",
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Esrafilzadeh, D, Zavabeti, A, Jalili, R, Atkin, P, Choi, J, Carey, BJ, Brkljača, R, O’Mullane, AP, Dickey, MD, Officer, DL, MacFarlane, DR, Daeneke, T & Kalantar-Zadeh, K 2019, 'Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces', Nature Communications, vol. 10, no. 1, 865. https://doi.org/10.1038/s41467-019-08824-8

Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces. / Esrafilzadeh, Dorna; Zavabeti, Ali; Jalili, Rouhollah; Atkin, Paul; Choi, Jay; Carey, Benjamin J.; Brkljača, Robert; O’Mullane, Anthony P.; Dickey, Michael D.; Officer, David L.; MacFarlane, Douglas R.; Daeneke, Torben; Kalantar-Zadeh, Kourosh.

In: Nature Communications, Vol. 10, No. 1, 865, 01.12.2019.

Research output: Contribution to journalArticleResearchpeer-review

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