Rhodium-Catalyzed Reactions of Propargylamines With CO/H

Eva M. Campi; Gary D. Fallon; Roy W. Jackson; Ylva Nilson

doi:10.1071/CH9921167

Rhodium-Catalyzed Reactions of Propargylamines With CO/H

Eva M. Campi, Gary D. Fallon, Roy W. Jackson, Ylva Nilson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

Rhodium- catalysed reactions of (arylpropargyl) arnines with CO/H2 give P-arylpyrroles in good yields.Reactions of(alkylpropargyl)amines gave alkylpyrroles together with butenolides which are formed in an unusual reaction that probably involves double carbonylation, reduction of one carbonyl functionand removal of the amine function by hydrogenolysis.The single-crystal X-ray structure of 5-methyl-N, 3-diphenylpyrrole-2-carboxamid is recorded.

Original language	English
Pages (from-to)	1167-1178
Number of pages	12
Journal	Australian Journal of Chemistry
Volume	45
Issue number	7
DOIs	https://doi.org/10.1071/CH9921167
Publication status	Published - 1 Jan 1992

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10.1071/CH9921167

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title = "Rhodium-Catalyzed Reactions of Propargylamines With CO/H",

abstract = "Rhodium- catalysed reactions of (arylpropargyl) arnines with CO/H2 give P-arylpyrroles in good yields.Reactions of(alkylpropargyl)amines gave alkylpyrroles together with butenolides which are formed in an unusual reaction that probably involves double carbonylation, reduction of one carbonyl functionand removal of the amine function by hydrogenolysis.The single-crystal X-ray structure of 5-methyl-N, 3-diphenylpyrrole-2-carboxamid is recorded.",

author = "Campi, \{Eva M.\} and Fallon, \{Gary D.\} and Jackson, \{Roy W.\} and Ylva Nilson",

year = "1992",

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AU - Campi, Eva M.

AU - Fallon, Gary D.

AU - Jackson, Roy W.

AU - Nilson, Ylva

PY - 1992/1/1

Y1 - 1992/1/1

N2 - Rhodium- catalysed reactions of (arylpropargyl) arnines with CO/H2 give P-arylpyrroles in good yields.Reactions of(alkylpropargyl)amines gave alkylpyrroles together with butenolides which are formed in an unusual reaction that probably involves double carbonylation, reduction of one carbonyl functionand removal of the amine function by hydrogenolysis.The single-crystal X-ray structure of 5-methyl-N, 3-diphenylpyrrole-2-carboxamid is recorded.

AB - Rhodium- catalysed reactions of (arylpropargyl) arnines with CO/H2 give P-arylpyrroles in good yields.Reactions of(alkylpropargyl)amines gave alkylpyrroles together with butenolides which are formed in an unusual reaction that probably involves double carbonylation, reduction of one carbonyl functionand removal of the amine function by hydrogenolysis.The single-crystal X-ray structure of 5-methyl-N, 3-diphenylpyrrole-2-carboxamid is recorded.

UR - https://www.scopus.com/pages/publications/84970564764

U2 - 10.1071/CH9921167

DO - 10.1071/CH9921167

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JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 7

ER -

Rhodium-Catalyzed Reactions of Propargylamines With CO/H

Abstract

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