Reversible surface functionalisation of emulsionlated porous polymers using dithiophenol maleimide functional macromolecules

A. M. Eissa; P. Wilson; C. Chen; J. Collins; M. Walker; D. M. Haddleton; N. R. Cameron

doi:10.1039/c7cc03811a

Reversible surface functionalisation of emulsionlated porous polymers using dithiophenol maleimide functional macromolecules

A. M. Eissa, P. Wilson, C. Chen, J. Collins, M. Walker, D. M. Haddleton, N. R. Cameron

Materials Science & Engineering

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

A new facile and efficient route for the chemical functionalisation of thiol-acrylate polyHIPE materials with responsive macromolecules using the highly emissive dithiomaleimide (DTM) linker is demonstrated. Functionalisation is found to be reversible upon addition of a thiol-containing compound, glutathione, resulting in switchable surface properties including fluorescence and wettability, hence broadening the scope of applications.

Original language	English
Pages (from-to)	9789-9792
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	70
DOIs	https://doi.org/10.1039/c7cc03811a
Publication status	Published - 2017

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10.1039/c7cc03811a

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Cite this

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title = "Reversible surface functionalisation of emulsionlated porous polymers using dithiophenol maleimide functional macromolecules",

abstract = "A new facile and efficient route for the chemical functionalisation of thiol-acrylate polyHIPE materials with responsive macromolecules using the highly emissive dithiomaleimide (DTM) linker is demonstrated. Functionalisation is found to be reversible upon addition of a thiol-containing compound, glutathione, resulting in switchable surface properties including fluorescence and wettability, hence broadening the scope of applications.",

author = "Eissa, {A. M.} and P. Wilson and C. Chen and J. Collins and M. Walker and Haddleton, {D. M.} and Cameron, {N. R.}",

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AU - Walker, M.

AU - Haddleton, D. M.

AU - Cameron, N. R.

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AB - A new facile and efficient route for the chemical functionalisation of thiol-acrylate polyHIPE materials with responsive macromolecules using the highly emissive dithiomaleimide (DTM) linker is demonstrated. Functionalisation is found to be reversible upon addition of a thiol-containing compound, glutathione, resulting in switchable surface properties including fluorescence and wettability, hence broadening the scope of applications.

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