Reversible redox reactions in an extended polyoxometalate framework solid

Chris Ritchie; Carsten Streb; Johannes Thiel; Scott G. Mitchell; Haralampos N. Miras; De Liang Long; Thomas Boyd; Robert D. Peacock; Thomas McGlone; Leroy Cronin

doi:10.1002/anie.200802594

Reversible redox reactions in an extended polyoxometalate framework solid

Chris Ritchie
, Carsten Streb
, Johannes Thiel
, Scott G. Mitchell
, Haralampos N. Miras
, De Liang Long
, Thomas Boyd
, Robert D. Peacock
, Thomas McGlone
, Leroy Cronin

Research output: Contribution to journal › Article › Research › peer-review

132 Citations (Scopus)

Abstract

(Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

Original language	English
Pages (from-to)	6881-6884
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	36
DOIs	https://doi.org/10.1002/anie.200802594
Publication status	Published - 25 Aug 2008
Externally published	Yes

Keywords

Cluster compounds
Framework materials
Polyoxometalates
Redox chemistry
Self-assembly

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10.1002/anie.200802594

Cite this

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abstract = "(Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.",

keywords = "Cluster compounds, Framework materials, Polyoxometalates, Redox chemistry, Self-assembly",

author = "Chris Ritchie and Carsten Streb and Johannes Thiel and Mitchell, \{Scott G.\} and Miras, \{Haralampos N.\} and Long, \{De Liang\} and Thomas Boyd and Peacock, \{Robert D.\} and Thomas McGlone and Leroy Cronin",

year = "2008",

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doi = "10.1002/anie.200802594",

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T1 - Reversible redox reactions in an extended polyoxometalate framework solid

AU - Ritchie, Chris

AU - Streb, Carsten

AU - Thiel, Johannes

AU - Mitchell, Scott G.

AU - Miras, Haralampos N.

AU - Long, De Liang

AU - Boyd, Thomas

AU - Peacock, Robert D.

AU - McGlone, Thomas

AU - Cronin, Leroy

PY - 2008/8/25

Y1 - 2008/8/25

N2 - (Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

AB - (Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

KW - Cluster compounds

KW - Framework materials

KW - Polyoxometalates

KW - Redox chemistry

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/53249123412

U2 - 10.1002/anie.200802594

DO - 10.1002/anie.200802594

M3 - Article

AN - SCOPUS:53249123412

SN - 1433-7851

VL - 47

SP - 6881

EP - 6884

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Reversible redox reactions in an extended polyoxometalate framework solid

Abstract

Keywords

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