Reversible redox reactions in an extended polyoxometalate framework solid

Chris Ritchie; Carsten Streb; Johannes Thiel; Scott G. Mitchell; Haralampos N. Miras; De Liang Long; Thomas Boyd; Robert D. Peacock; Thomas McGlone; Leroy Cronin

doi:10.1002/anie.200802594

Reversible redox reactions in an extended polyoxometalate framework solid

Chris Ritchie, Carsten Streb, Johannes Thiel, Scott G. Mitchell, Haralampos N. Miras, De Liang Long, Thomas Boyd, Robert D. Peacock, Thomas McGlone, Leroy Cronin

Research output: Contribution to journal › Article › Research › peer-review

126 Citations (Scopus)

Abstract

(Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

Original language	English
Pages (from-to)	6881-6884
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	36
DOIs	https://doi.org/10.1002/anie.200802594
Publication status	Published - 25 Aug 2008
Externally published	Yes

Keywords

Cluster compounds
Framework materials
Polyoxometalates
Redox chemistry
Self-assembly

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10.1002/anie.200802594

Cite this

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AU - Ritchie, Chris

AU - Streb, Carsten

AU - Thiel, Johannes

AU - Mitchell, Scott G.

AU - Miras, Haralampos N.

AU - Long, De Liang

AU - Boyd, Thomas

AU - Peacock, Robert D.

AU - McGlone, Thomas

AU - Cronin, Leroy

PY - 2008/8/25

Y1 - 2008/8/25

N2 - (Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

AB - (Figure Presented) Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent (see picture). Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.

KW - Cluster compounds

KW - Framework materials

KW - Polyoxometalates

KW - Redox chemistry

KW - Self-assembly

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U2 - 10.1002/anie.200802594

DO - 10.1002/anie.200802594

M3 - Article

AN - SCOPUS:53249123412

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Reversible redox reactions in an extended polyoxometalate framework solid

Abstract

Keywords

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