Reversible light-driven polymerization of polyoxometalate tethered with coumarin molecules

Unsong Tong; Wei Chen; Chris Ritchie; Xiaoting Wang; Yu Fei Song

doi:10.1002/chem.201303933

Reversible light-driven polymerization of polyoxometalate tethered with coumarin molecules

Unsong Tong, Wei Chen, Chris Ritchie, Xiaoting Wang, Yu Fei Song

Research output: Contribution to journal › Article › Research › peer-review

41 Citations (Scopus)

Abstract

A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by ¹H NMR, ¹³C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This organic-inorganic hybrid compound can undergo reversible light-driven polymerization and this process has been characterized in detail. Polymerizing POMs: A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by ¹H NMR, ¹³C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This compound can undergo reversible light-driven polymerization (see scheme) and this process has been characterized in detail.

Original language	English
Pages (from-to)	1500-1504
Number of pages	5
Journal	Chemistry - A European Journal
Volume	20
Issue number	6
DOIs	https://doi.org/10.1002/chem.201303933
Publication status	Published - 3 Feb 2014
Externally published	Yes

Keywords

coumarins
covalent functionalization
photopolymerization
polyoxometalates

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10.1002/chem.201303933

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title = "Reversible light-driven polymerization of polyoxometalate tethered with coumarin molecules",

abstract = "A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by 1H NMR, 13C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This organic-inorganic hybrid compound can undergo reversible light-driven polymerization and this process has been characterized in detail. Polymerizing POMs: A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by 1H NMR, 13C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This compound can undergo reversible light-driven polymerization (see scheme) and this process has been characterized in detail.",

keywords = "coumarins, covalent functionalization, photopolymerization, polyoxometalates",

author = "Unsong Tong and Wei Chen and Chris Ritchie and Xiaoting Wang and Song, \{Yu Fei\}",

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AU - Tong, Unsong

AU - Chen, Wei

AU - Ritchie, Chris

AU - Wang, Xiaoting

AU - Song, Yu Fei

PY - 2014/2/3

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AB - A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by 1H NMR, 13C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This organic-inorganic hybrid compound can undergo reversible light-driven polymerization and this process has been characterized in detail. Polymerizing POMs: A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by 1H NMR, 13C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This compound can undergo reversible light-driven polymerization (see scheme) and this process has been characterized in detail.

KW - coumarins

KW - covalent functionalization

KW - photopolymerization

KW - polyoxometalates

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DO - 10.1002/chem.201303933

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 6

ER -

Reversible light-driven polymerization of polyoxometalate tethered with coumarin molecules

Abstract

Keywords

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