Reversible Insertion Reactions of a Platinum Germylene Complex

Kyle E. Litz; Kenneth Henderson; Randall W. Gourley; Mark M. Banaszak Holl

doi:10.1021/om00011a015

Reversible Insertion Reactions of a Platinum Germylene Complex

Kyle E. Litz, Kenneth Henderson, Randall W. Gourley, Mark M. Banaszak Holl

Research output: Contribution to journal › Article › Research › peer-review

72 Citations (Scopus)

Abstract

Dihydrogen and carbon dioxide react reversibly with the three-coordinate complex (Et₃P)₂PtGe[N(SiMe₃)₂]₂. These reactions demonstrate the ability of germylenes to act as strong supporting ligands, while introducing new modes of reactivity via formal Ge(II) / Ge(IV) interconversion.

Original language	English
Pages (from-to)	5008-5010
Number of pages	3
Journal	Organometallics
Volume	14
Issue number	11
DOIs	https://doi.org/10.1021/om00011a015
Publication status	Published - 1 Jan 1995
Externally published	Yes

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title = "Reversible Insertion Reactions of a Platinum Germylene Complex",

abstract = "Dihydrogen and carbon dioxide react reversibly with the three-coordinate complex (Et3P)2PtGe[N(SiMe3)2]2. These reactions demonstrate the ability of germylenes to act as strong supporting ligands, while introducing new modes of reactivity via formal Ge(II) / Ge(IV) interconversion.",

author = "Litz, {Kyle E.} and Kenneth Henderson and Gourley, {Randall W.} and {Banaszak Holl}, {Mark M.}",

year = "1995",

month = jan,

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doi = "10.1021/om00011a015",

language = "English",

volume = "14",

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journal = "Organometallics",

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T1 - Reversible Insertion Reactions of a Platinum Germylene Complex

AU - Litz, Kyle E.

AU - Henderson, Kenneth

AU - Gourley, Randall W.

AU - Banaszak Holl, Mark M.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Dihydrogen and carbon dioxide react reversibly with the three-coordinate complex (Et3P)2PtGe[N(SiMe3)2]2. These reactions demonstrate the ability of germylenes to act as strong supporting ligands, while introducing new modes of reactivity via formal Ge(II) / Ge(IV) interconversion.

AB - Dihydrogen and carbon dioxide react reversibly with the three-coordinate complex (Et3P)2PtGe[N(SiMe3)2]2. These reactions demonstrate the ability of germylenes to act as strong supporting ligands, while introducing new modes of reactivity via formal Ge(II) / Ge(IV) interconversion.

UR - http://www.scopus.com/inward/record.url?scp=0000062998&partnerID=8YFLogxK

U2 - 10.1021/om00011a015

DO - 10.1021/om00011a015

M3 - Article

AN - SCOPUS:0000062998

SN - 0276-7333

VL - 14

SP - 5008

EP - 5010

JO - Organometallics

JF - Organometallics

IS - 11

ER -

Reversible Insertion Reactions of a Platinum Germylene Complex

Abstract

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