Reversibility of the Zn(II) → Zn electrode reaction in the application of polarographic theory to the study of the fluoride complexes of zinc

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Abstract

Polarographic measurements on aqueous solutions containing zinc and fluoride ions have shown the existence of the species ZnF+ with a stability constant of 9 at 30°, at an ionic strength of 1.0. The zincfluoride system was evaluated by the polarographic method for reversible reduction after a detailed study to determine conditions under which the zinc system is reversibly reduced in fluoride media.

Original languageEnglish
Pages (from-to)109-118
Number of pages10
JournalJournal of Electroanalytical Chemistry
Volume20
Issue number1
Publication statusPublished - 1 Jan 1989
Externally publishedYes

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