Projects per year
Abstract
Two-dimensional transition metal dichalcogenides (TMDs) hold great potential for future low-energy optoelectronics owing to their unique electronic, optical, and mechanical properties. Chemical vapor deposition (CVD) is the technique widely used for the synthesis of large-area TMDs. However, due to high sensitivity to the growth environment, reliable synthesis of monolayer TMDs via CVD remains challenging. Here a controllable CVD process is developed for large-area synthesis of monolayer WS2 crystals, films, and in-plane graphene–WS2 heterostructures by cleaning the reaction tube with hydrochloric acid, sulfuric acid, and aqua regia. The concise cleaning process can remove the residual contaminates attached to the CVD reaction tube and crucibles, reducing the nucleation density but enhancing the diffusion length of WS2 species. The photoluminescence (PL) mappings of a WS2 single crystal and film reveal that the extraordinary PL around the edges of a triangular single crystal is induced by ambient water intercalation at the WS2–sapphire interface. The extraordinary PL can be controlled by the choice of substrates with different wettabilities.
Original language | English |
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Article number | 1701347 |
Number of pages | 9 |
Journal | Advanced Optical Materials |
Volume | 6 |
Issue number | 12 |
DOIs | |
Publication status | Published - 19 Jun 2018 |
Keywords
- biexcitons
- chemical vapor deposition
- dielectric screening
- photoluminescence
- transition metal dichalcogenides
Projects
- 3 Finished
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ARC Centre of Excellence in Future Low-energy Electronics Technologies
Fuhrer, M. (Primary Chief Investigator (PCI)), Bao, Q. (Chief Investigator (CI)), Culcer, D. (Chief Investigator (CI)), Davis, M. (Chief Investigator (CI)), Davis, J. A. (Chief Investigator (CI)), Hamilton, A. (Chief Investigator (CI)), Helmerson, K. (Chief Investigator (CI)), Klochan, O. (Chief Investigator (CI)), Medhekar, N. (Chief Investigator (CI)), Ostrovskaya, E. A. (Chief Investigator (CI)), Parish, M. (Chief Investigator (CI)), Schiffrin, A. (Chief Investigator (CI)), Seidel, J. (Chief Investigator (CI)), Sushkov, O. (Chief Investigator (CI)), Valanoor, N. (Chief Investigator (CI)), Wang, X. (Chief Investigator (CI)), Galitskiy, V. (Partner Investigator (PI)), Gurarie, V. (Partner Investigator (PI)), Hannon, J. (Partner Investigator (PI)), Höfling, S. (Partner Investigator (PI)), Hone, J. (Partner Investigator (PI)), Rule, K. C. (Partner Investigator (PI)), Krausz, F. (Partner Investigator (PI)), Littlewood, P. (Partner Investigator (PI)), MacDonald, A. (Partner Investigator (PI)), Neto, A. (Partner Investigator (PI)), Oezyilmaz, B. (Partner Investigator (PI)), Paglione, J. (Partner Investigator (PI)), Phillips, W. (Partner Investigator (PI)), Spielman, I. (Partner Investigator (PI)), Tadich, A. (Partner Investigator (PI)), Xue, Q. (Partner Investigator (PI)), Cole, J. (Chief Investigator (CI)), Perali, A. (Partner Investigator (PI)), Neilson, D. (Partner Investigator (PI)), Sek, G. (Partner Investigator (PI)), Gaston, N. (Partner Investigator (PI)), Hodgkiss, J. M. (Partner Investigator (PI)), Tang, M. (Partner Investigator (PI)), Karel, J. (Chief Investigator (CI)), Nguyen, T.-L. (Project Manager), Adam, S. (Partner Investigator (PI)), Granville, S. (Partner Investigator (PI)), Kumar, P. V. (Chief Investigator (CI)) & Daeneke, T. (Chief Investigator (CI))
Australian Research Council (ARC), Monash University – Internal School Contribution, Monash University – Internal Department Contribution, Monash University – Internal Faculty Contribution, Monash University – Internal University Contribution, University of Wollongong, University of Queensland , Tsinghua University, University of New South Wales (UNSW), Australian National University (ANU), RMIT University, Swinburne University of Technology
29/06/17 → 28/06/24
Project: Research
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Semiconductor quantum wells at the atomic scale
Fuhrer, M. (Primary Chief Investigator (PCI)) & Adam, S. (Partner Investigator (PI))
Australian Research Council (ARC), Monash University, National University of Singapore (NUS)
1/01/15 → 31/12/20
Project: Research
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Understanding and Controlling the Properties of Dirac Electronic Materials
Fuhrer, M. (Primary Chief Investigator (PCI))
Australian Research Council (ARC)
14/01/13 → 30/09/18
Project: Research
Equipment
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Melbourne Centre for Nanofabrication (MCN)
Langelier, S. (Manager)
Office of the Vice-Provost (Research and Research Infrastructure)Facility/equipment: Facility