Redox properties of mononuclear and triply-bridged binuclear thiolato anions of oxomolybdenum(V)

Julie R. Bradbury, Anthony G. Wedd, Alan M. Bond

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Abstract

Interconversion of mononuclear [MoVO(SR)4] - (1; R = aryl or alkyl) and triply-bridged, binuclear [Mo V2O2(SR)6Z]- (2; Z = OMe, OEt, or SCH2Ph) anions occurs via redox processes involving both the molybdenum and ligand thiolate centres.

Original languageEnglish
Pages (from-to)1022-1025
Number of pages4
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
DOIs
Publication statusPublished - 1 Dec 1979

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