Recent progress in synchrotron-based frequency-domain Fourier-transform THz-EPR

Joscha Nehrkorn, Karsten Holldack, Robert Bittl, Alexander Schnegg

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18 Citations (Scopus)

Abstract

We describe frequency-domain Fourier-transform THz-EPR as a method to assign spin-coupling parameters of high-spin (S > 1/2) systems with very large zero-field splittings. The instrumental foundations of synchrotron-based FD-FT THz-EPR are presented, alongside with a discussion of frequency-domain EPR simulation routines. The capabilities of this approach is demonstrated for selected mono- and multinuclear HS systems. Finally, we discuss remaining challenges and give an outlook on the future prospects of the technique.

Original languageEnglish
Pages (from-to)10-19
Number of pages10
JournalJournal of Magnetic Resonance
Volume280
DOIs
Publication statusPublished - 1 Jul 2017
Externally publishedYes

Keywords

  • Frequency-domain EPR spectroscopy
  • High-spin transition-metal ion
  • Zero-field splitting

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