TY - JOUR
T1 - Rearrangements in the formation of some π-allylpalladium compounds
AU - Gray, G. A.
AU - Jackson, W. R.
AU - Rooney, J. J.
PY - 1970/1/1
Y1 - 1970/1/1
N2 - A reaction of p-menth-1 (2)-en-3-ol with palladium(II) chloride, lithium chloride, and carbon monoxide which was worked up as soon as the passage of gas had ceased gave di-μ-chloro-bis-[(1,2,3-trihapto-p-menth-1-ene)palladium(II)] (2). When the mixture was set aside for several days di-μ-chloro-bis-[(3,4, 8-trihapto-p-menth-3-ene)palladium(II)] (3) was isolated. The preparation of (3) from other cyclic monoterpene derivatives is described.
AB - A reaction of p-menth-1 (2)-en-3-ol with palladium(II) chloride, lithium chloride, and carbon monoxide which was worked up as soon as the passage of gas had ceased gave di-μ-chloro-bis-[(1,2,3-trihapto-p-menth-1-ene)palladium(II)] (2). When the mixture was set aside for several days di-μ-chloro-bis-[(3,4, 8-trihapto-p-menth-3-ene)palladium(II)] (3) was isolated. The preparation of (3) from other cyclic monoterpene derivatives is described.
UR - http://www.scopus.com/inward/record.url?scp=37049133939&partnerID=8YFLogxK
U2 - 10.1039/J39700001788
DO - 10.1039/J39700001788
M3 - Article
AN - SCOPUS:37049133939
SN - 0022-4952
SP - 1788
EP - 1789
JO - Journal of the Chemical Society C: Organic Chemistry
JF - Journal of the Chemical Society C: Organic Chemistry
IS - 13
ER -