Reactions over metal catalysts. Part I. The stereochemistry of hydrogenolysis of 3-acetoxynortricyclene

M. Nasseem Akhtar, John J. Rooney, W. Roy Jackson

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Abstract

Hydrogenolysis of 3-acetoxynortricyclene gives a mixture of acetoxynorbornanes in which 7-acetoxynorbornane predominates. When deuterium is used in the reaction, the n.m.r. spectra of this product shows a stereospecific deuterium incorporation into 2,6-endo-positions. The reactions of acetoxyquadricyclene and 7-acetoxynorbornadiene with deuterium are also discussed.

Original languageEnglish
Pages (from-to)595-597
Number of pages3
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number5
DOIs
Publication statusPublished - 1 Jan 1976

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