Abstract
Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.
| Original language | English |
|---|---|
| Pages (from-to) | 1509-1516 |
| Number of pages | 8 |
| Journal | Australian Journal of Chemistry |
| Volume | 30 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 1 Jan 1977 |
Cite this
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Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes. / Nasseem Akhtar, M.; Rooney, John J.; Samman, Nicholas G.; Hügel, Helmut M.; Roy Jackson, W.; Nicolson, David M.; Rash, Douglas.
In: Australian Journal of Chemistry, Vol. 30, No. 7, 01.01.1977, p. 1509-1516.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes
AU - Nasseem Akhtar, M.
AU - Rooney, John J.
AU - Samman, Nicholas G.
AU - Hügel, Helmut M.
AU - Roy Jackson, W.
AU - Nicolson, David M.
AU - Rash, Douglas
PY - 1977/1/1
Y1 - 1977/1/1
N2 - Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.
AB - Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.
UR - http://www.scopus.com/inward/record.url?scp=84971023659&partnerID=8YFLogxK
U2 - 10.1071/CH9771509
DO - 10.1071/CH9771509
M3 - Article
VL - 30
SP - 1509
EP - 1516
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 7
ER -