Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes

M. Nasseem Akhtar; John J. Rooney; Nicholas G. Samman; Helmut M. Hügel; W. Roy Jackson; David M. Nicolson; Douglas Rash

doi:10.1071/CH9771509

Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes

M. Nasseem Akhtar, John J. Rooney, Nicholas G. Samman, Helmut M. Hügel, W. Roy Jackson, David M. Nicolson, Douglas Rash

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.

Original language	English
Pages (from-to)	1509-1516
Number of pages	8
Journal	Australian Journal of Chemistry
Volume	30
Issue number	7
DOIs	https://doi.org/10.1071/CH9771509
Publication status	Published - 1 Jan 1977

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10.1071/CH9771509

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Cite this

@article{ee8a6d671dcc416586bcd4e88d856bb0,

title = "Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes",

abstract = "Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.",

author = "{Nasseem Akhtar}, M. and Rooney, {John J.} and Samman, {Nicholas G.} and H{\"u}gel, {Helmut M.} and {Roy Jackson}, W. and Nicolson, {David M.} and Douglas Rash",

year = "1977",

month = jan,

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doi = "10.1071/CH9771509",

language = "English",

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journal = "Australian Journal of Chemistry",

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Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes. / Nasseem Akhtar, M.; Rooney, John J.; Samman, Nicholas G.; Hügel, Helmut M.; Roy Jackson, W.; Nicolson, David M.; Rash, Douglas.

In: Australian Journal of Chemistry, Vol. 30, No. 7, 01.01.1977, p. 1509-1516.

Research output: Contribution to journal › Article › Research › peer-review

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AU - Rooney, John J.

AU - Samman, Nicholas G.

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AU - Roy Jackson, W.

AU - Nicolson, David M.

AU - Rash, Douglas

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AB - Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.

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