Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes

M. Nasseem Akhtar, John J. Rooney, Nicholas G. Samman, Helmut M. Hügel, W. Roy Jackson, David M. Nicolson, Douglas Rash

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5 Citations (Scopus)

Abstract

Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.

Original languageEnglish
Pages (from-to)1509-1516
Number of pages8
JournalAustralian Journal of Chemistry
Volume30
Issue number7
DOIs
Publication statusPublished - 1 Jan 1977

Cite this

Nasseem Akhtar, M., Rooney, J. J., Samman, N. G., Hügel, H. M., Roy Jackson, W., Nicolson, D. M., & Rash, D. (1977). Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes. Australian Journal of Chemistry, 30(7), 1509-1516. https://doi.org/10.1071/CH9771509
Nasseem Akhtar, M. ; Rooney, John J. ; Samman, Nicholas G. ; Hügel, Helmut M. ; Roy Jackson, W. ; Nicolson, David M. ; Rash, Douglas. / Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes. In: Australian Journal of Chemistry. 1977 ; Vol. 30, No. 7. pp. 1509-1516.
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Nasseem Akhtar, M, Rooney, JJ, Samman, NG, Hügel, HM, Roy Jackson, W, Nicolson, DM & Rash, D 1977, 'Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes', Australian Journal of Chemistry, vol. 30, no. 7, pp. 1509-1516. https://doi.org/10.1071/CH9771509

Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes. / Nasseem Akhtar, M.; Rooney, John J.; Samman, Nicholas G.; Hügel, Helmut M.; Roy Jackson, W.; Nicolson, David M.; Rash, Douglas.

In: Australian Journal of Chemistry, Vol. 30, No. 7, 01.01.1977, p. 1509-1516.

Research output: Contribution to journalArticleResearchpeer-review

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AB - Hydrogenolysis of 3-methylnortricyclene over platinum in acetic acid solution leads to the formation of almost equal amounts of 7-methylnorbornane and exo-2-methylnorbornane with much smaller amounts of the endo-2-methyl compound. In contrast, reactions over supported metal catalysts in the vapour phase lead to a predominance of the 2-methyl compounds. Similar trends have been observed in the hydrogenolyses of 3-cyclohexyl- and 3-acetoxy-nortricyclenes.

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Nasseem Akhtar M, Rooney JJ, Samman NG, Hügel HM, Roy Jackson W, Nicolson DM et al. Reactions over metal catalysts. III* Hydrogenolysis of some 3-substituted nortricyclenes. Australian Journal of Chemistry. 1977 Jan 1;30(7):1509-1516. https://doi.org/10.1071/CH9771509