TY - JOUR
T1 - Reactions of uranium hydride with some organic and organometallic compounds
AU - Deacon, G. B.
AU - Tuong, T. D.
AU - Franklin, G. R.
PY - 1986/1/15
Y1 - 1986/1/15
N2 - Uranium hydride reduces chloro-, bromo-, and iodo-benzene to benzene and biphenyl, nitrobenzene to azoxy- and azo-benzene, azoxybenzene to azobenzene, and triphenylarsine oxide to triphenylarsine in boiling tetrahydrofuran and/or in the absence of added solvent at 130-170 °C. In tetrahydrofuran, benzoyl chloride gives low yields of butyl benzoate and benzil. A wide range of substrates, e.g. PhF, p-(O2N)2C6H4, PhCHO, C5H5Tl, and Ph3PO, fails to react with UH3.
AB - Uranium hydride reduces chloro-, bromo-, and iodo-benzene to benzene and biphenyl, nitrobenzene to azoxy- and azo-benzene, azoxybenzene to azobenzene, and triphenylarsine oxide to triphenylarsine in boiling tetrahydrofuran and/or in the absence of added solvent at 130-170 °C. In tetrahydrofuran, benzoyl chloride gives low yields of butyl benzoate and benzil. A wide range of substrates, e.g. PhF, p-(O2N)2C6H4, PhCHO, C5H5Tl, and Ph3PO, fails to react with UH3.
UR - http://www.scopus.com/inward/record.url?scp=8344243273&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)84651-4
DO - 10.1016/S0020-1693(00)84651-4
M3 - Article
AN - SCOPUS:8344243273
SN - 0020-1693
VL - 111
SP - 193
EP - 196
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 2
ER -