Reactions of diorganoytterbium compounds with ketones and aldehydes

G. B. Deacon; T. D. Tuong

doi:10.1016/S0022-328X(00)82946-0

Reactions of diorganoytterbium compounds with ketones and aldehydes

G. B. Deacon, T. D. Tuong

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

37 Citations (Scopus)

Abstract

Reactions of the diorganolanthanoids R₂Yb (R = PhCC or C₆F₅) with aldehydes (R′CHO) and ketones (R′₂CO) (R = Me or Ph) followed by hydrolysis generally gives the alcohols RR′CH(OH) or RR′₂COH, but, with benzophenone, reduction giving benzopinacol either competes (R = PhCC) or is predominant (R = C₆F₅).

Original language	English
Pages (from-to)	4-6
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	205
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)82946-0
Publication status	Published - 27 Jan 1981

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10.1016/S0022-328X(00)82946-0

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abstract = "Reactions of the diorganolanthanoids R2Yb (R = PhCC or C6F5) with aldehydes (R′CHO) and ketones (R′2CO) (R = Me or Ph) followed by hydrolysis generally gives the alcohols RR′CH(OH) or RR′2COH, but, with benzophenone, reduction giving benzopinacol either competes (R = PhCC) or is predominant (R = C6F5). ",

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AB - Reactions of the diorganolanthanoids R2Yb (R = PhCC or C6F5) with aldehydes (R′CHO) and ketones (R′2CO) (R = Me or Ph) followed by hydrolysis generally gives the alcohols RR′CH(OH) or RR′2COH, but, with benzophenone, reduction giving benzopinacol either competes (R = PhCC) or is predominant (R = C6F5).

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