TY - JOUR
T1 - Reaction of triruthenium dodecacarbonyl with high-area rare earth oxides
AU - Bruce, Linda A.
AU - Hoang, Manh
AU - Hughes, Anthony E.
AU - Turney, Terence W.
PY - 1997/1/1
Y1 - 1997/1/1
N2 - Reaction of Ru3(CO)12 with high area (≥ 45 m2 g-1) oxides of the rare earths, La, Ce, Pr, Tb, Ho and Yb has been studied by IR and X-ray photoelectron spectroscopy. Evidence is presented for formation of surface species [ (OC)2Ru(OM)2]n at ≤ 2% (wt./wt.) Ru loading for all oxides and for a surface cluster, possibly [Ru3(μ-H) (CO)10(μ-OM) ], at 5% (wt./wt,) metal loadings for Ce and Ho oxides.
AB - Reaction of Ru3(CO)12 with high area (≥ 45 m2 g-1) oxides of the rare earths, La, Ce, Pr, Tb, Ho and Yb has been studied by IR and X-ray photoelectron spectroscopy. Evidence is presented for formation of surface species [ (OC)2Ru(OM)2]n at ≤ 2% (wt./wt.) Ru loading for all oxides and for a surface cluster, possibly [Ru3(μ-H) (CO)10(μ-OM) ], at 5% (wt./wt,) metal loadings for Ce and Ho oxides.
KW - Rare earth oxide complexes
KW - Ruthenium complexes
UR - http://www.scopus.com/inward/record.url?scp=0040515124&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(96)05132-8
DO - 10.1016/S0020-1693(96)05132-8
M3 - Article
AN - SCOPUS:0040515124
SN - 0020-1693
VL - 254
SP - 37
EP - 41
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -