Reaction of t-butoxy radicals with norbornadiene

W. Ken Busfield; Ian D. Jenkins; San H. Thang; Ezio Rizzardo; David H. Solomon

doi:10.1016/S0040-4039(01)80858-3

Reaction of t-butoxy radicals with norbornadiene

W. Ken Busfield, Ian D. Jenkins, San H. Thang, Ezio Rizzardo, David H. Solomon

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

95 percent of the reaction of t-butoxy radical with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearrangement involving a 1,3-H shift and some radical abstraction observed for the first time.

Original language	English
Pages (from-to)	5081-5084
Number of pages	4
Journal	Tetrahedron Letters
Volume	26
Issue number	41
DOIs	https://doi.org/10.1016/S0040-4039(01)80858-3
Publication status	Published - 1 Jan 1985

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10.1016/S0040-4039(01)80858-3

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Cite this

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title = "Reaction of t-butoxy radicals with norbornadiene",

abstract = "95 percent of the reaction of t-butoxy radical with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearrangement involving a 1,3-H shift and some radical abstraction observed for the first time.",

author = "Busfield, {W. Ken} and Jenkins, {Ian D.} and Thang, {San H.} and Ezio Rizzardo and Solomon, {David H.}",

year = "1985",

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journal = "Tetrahedron Letters",

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T1 - Reaction of t-butoxy radicals with norbornadiene

AU - Busfield, W. Ken

AU - Jenkins, Ian D.

AU - Thang, San H.

AU - Rizzardo, Ezio

AU - Solomon, David H.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - 95 percent of the reaction of t-butoxy radical with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearrangement involving a 1,3-H shift and some radical abstraction observed for the first time.

AB - 95 percent of the reaction of t-butoxy radical with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearrangement involving a 1,3-H shift and some radical abstraction observed for the first time.

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U2 - 10.1016/S0040-4039(01)80858-3

DO - 10.1016/S0040-4039(01)80858-3

M3 - Article

AN - SCOPUS:0000550818

VL - 26

SP - 5081

EP - 5084

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 41

ER -