Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N2)(diphos) 2]

Robert A. Cable; Michael Green; Robert E. Mackenzie; Peter L. Timms; Terence W. Turney

doi:10.1039/C3976000270b

Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N₂)(diphos) ₂]

Robert A. Cable, Michael Green, Robert E. Mackenzie, Peter L. Timms, Terence W. Turney

Research output: Contribution to journal › Article › Research › peer-review

43 Citations (Scopus)

Abstract

Reaction of [Fe(1,5-C₈H₁₂)₂] with P(OMe)₃ affords [Fe(1,3-C₈H₁₂){P(OMe) ₃}₃], whereas, PF₃, Co, and Bu^tNC give [Fe(1,5-C₈H₁₂)L₃] (L = PF₃, CO, or Bu^tNC); in contrast Ph₂PCH₂CH ₂PPh₂ and dinitrogen give the Fe⁰ dinitrogen complex [Fe(N₂)(Ph₂PCH₂CH₂PPh ₂)].

Original language	English
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/C3976000270b
Publication status	Published - 1 Dec 1976
Externally published	Yes

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10.1039/C3976000270b

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Cable, R. A., Green, M., Mackenzie, R. E., Timms, P. L., & Turney, T. W. (1976). Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N₂)(diphos) ₂]. Journal of the Chemical Society, Chemical Communications, (7). https://doi.org/10.1039/C3976000270b

@article{19a76c254fe444d4b90986075a07627b,

title = "Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N2)(diphos) 2]",

abstract = "Reaction of [Fe(1,5-C8H12)2] with P(OMe)3 affords [Fe(1,3-C8H12){P(OMe) 3}3], whereas, PF3, Co, and ButNC give [Fe(1,5-C8H12)L3] (L = PF3, CO, or ButNC); in contrast Ph2PCH2CH 2PPh2 and dinitrogen give the Fe0 dinitrogen complex [Fe(N2)(Ph2PCH2CH2PPh 2)].",

author = "Cable, {Robert A.} and Michael Green and Mackenzie, {Robert E.} and Timms, {Peter L.} and Turney, {Terence W.}",

year = "1976",

month = dec,

day = "1",

doi = "10.1039/C3976000270b",

language = "English",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "The Royal Society of Chemistry",

number = "7",

}

Cable, RA, Green, M, Mackenzie, RE, Timms, PL & Turney, TW 1976, 'Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N₂)(diphos) ₂]', Journal of the Chemical Society, Chemical Communications, no. 7. https://doi.org/10.1039/C3976000270b

Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N₂)(diphos) ₂]. / Cable, Robert A.; Green, Michael; Mackenzie, Robert E. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 7, 01.12.1976.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N2)(diphos) 2]

AU - Cable, Robert A.

AU - Green, Michael

AU - Mackenzie, Robert E.

AU - Timms, Peter L.

AU - Turney, Terence W.

PY - 1976/12/1

Y1 - 1976/12/1

N2 - Reaction of [Fe(1,5-C8H12)2] with P(OMe)3 affords [Fe(1,3-C8H12){P(OMe) 3}3], whereas, PF3, Co, and ButNC give [Fe(1,5-C8H12)L3] (L = PF3, CO, or ButNC); in contrast Ph2PCH2CH 2PPh2 and dinitrogen give the Fe0 dinitrogen complex [Fe(N2)(Ph2PCH2CH2PPh 2)].

AB - Reaction of [Fe(1,5-C8H12)2] with P(OMe)3 affords [Fe(1,3-C8H12){P(OMe) 3}3], whereas, PF3, Co, and ButNC give [Fe(1,5-C8H12)L3] (L = PF3, CO, or ButNC); in contrast Ph2PCH2CH 2PPh2 and dinitrogen give the Fe0 dinitrogen complex [Fe(N2)(Ph2PCH2CH2PPh 2)].

UR - http://www.scopus.com/inward/record.url?scp=37049098203&partnerID=8YFLogxK

U2 - 10.1039/C3976000270b

DO - 10.1039/C3976000270b

M3 - Article

AN - SCOPUS:37049098203

SN - 0022-4936

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 7

ER -

Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N2)(diphos) 2]

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Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N₂)(diphos) ₂]