Rare-earth N,N′-diarylformamidinate complexes

Glen B. Deacon; Md Elius Hossain; Peter C. Junk; Mehdi Salehisaki

doi:10.1016/j.ccr.2017.02.011

Rare-earth N,N′-diarylformamidinate complexes

Glen B. Deacon, Md Elius Hossain, Peter C. Junk, Mehdi Salehisaki

School of Chemistry

Research output: Contribution to journal › Review Article › Research › peer-review

30 Citations (Scopus)

Abstract

This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N′-bis(aryl)formamidinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.

Original language	English
Pages (from-to)	247-265
Number of pages	19
Journal	Coordination Chemistry Reviews
Volume	340
DOIs	https://doi.org/10.1016/j.ccr.2017.02.011
Publication status	Published - 1 Jun 2017

Keywords

Formamidinates
Lanthanoid(II)
Lanthanoid(III)
Lanthanoid(IV)
Lanthanoids

Access to Document

10.1016/j.ccr.2017.02.011

Link to publication in Scopus

Cite this

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title = "Rare-earth N,N′-diarylformamidinate complexes",

abstract = "This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N′-bis(aryl)formamidinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.",

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AU - Junk, Peter C.

AU - Salehisaki, Mehdi

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KW - Lanthanoid(II)

KW - Lanthanoid(III)

KW - Lanthanoid(IV)

KW - Lanthanoids

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