Rare-earth N,N′-diarylformamidinate complexes

Glen B. Deacon, Md Elius Hossain, Peter C. Junk, Mehdi Salehisaki

Research output: Contribution to journalReview ArticleResearchpeer-review

30 Citations (Scopus)

Abstract

This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N′-bis(aryl)formamidinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.

Original languageEnglish
Pages (from-to)247-265
Number of pages19
JournalCoordination Chemistry Reviews
Volume340
DOIs
Publication statusPublished - 1 Jun 2017

Keywords

  • Formamidinates
  • Lanthanoid(II)
  • Lanthanoid(III)
  • Lanthanoid(IV)
  • Lanthanoids

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