Rare-earth N,N′-diarylformamidinate complexes

Glen B. Deacon; Md Elius Hossain; Peter C. Junk; Mehdi Salehisaki

doi:10.1016/j.ccr.2017.02.011

Rare-earth N,N′-diarylformamidinate complexes

Glen B. Deacon, Md Elius Hossain, Peter C. Junk, Mehdi Salehisaki

School of Chemistry

Research output: Contribution to journal › Review Article › Research › peer-review

43 Citations (Scopus)

Abstract

This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N′-bis(aryl)formamidinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.

Original language	English
Pages (from-to)	247-265
Number of pages	19
Journal	Coordination Chemistry Reviews
Volume	340
DOIs	https://doi.org/10.1016/j.ccr.2017.02.011
Publication status	Published - 1 Jun 2017

Keywords

Formamidinates
Lanthanoid(II)
Lanthanoid(III)
Lanthanoid(IV)
Lanthanoids

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10.1016/j.ccr.2017.02.011

Cite this

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abstract = "This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N′-bis(aryl)formamidinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.",

keywords = "Formamidinates, Lanthanoid(II), Lanthanoid(III), Lanthanoid(IV), Lanthanoids",

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AU - Deacon, Glen B.

AU - Hossain, Md Elius

AU - Junk, Peter C.

AU - Salehisaki, Mehdi

PY - 2017/6/1

Y1 - 2017/6/1

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AB - This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N′-bis(aryl)formamidinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.

KW - Formamidinates

KW - Lanthanoid(II)

KW - Lanthanoid(III)

KW - Lanthanoid(IV)

KW - Lanthanoids

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JF - Coordination Chemistry Reviews

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ER -

Rare-earth N,N′-diarylformamidinate complexes

Abstract

Keywords

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Reactive metal-organics embracing the rare earth and alkaline earth metals

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Rare-earth N,N′-diarylformamidinate complexes

Abstract

Keywords

Access to Document

Other files and links

Projects

Reactive metal-organics embracing the rare earth and alkaline earth metals

Cite this