Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support

Ezzatollah Shamsaei; Ze-Xian Low; Xiaocheng Lin; Alireza Mayahi; Huiyuan Liu; Xiwang Zhang; Jefferson Zhe Liu; Huanting Wang

doi:10.1039/c5cc03537f

Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support

Ezzatollah Shamsaei, Ze-Xian Low, Xiaocheng Lin, Alireza Mayahi, Huiyuan Liu, Xiwang Zhang, Jefferson Zhe Liu, Huanting Wang

Research output: Contribution to journal › Article › Research › peer-review

113 Citations (Scopus)

Abstract

Ultrathin ZIF-8 membranes with a thickness of around 200 nm
were prepared by chemical vapour modification of surface chemistry
and nanopores of an asymmetric bromomethylated poly(2,6-
dimethyl-1,4-phenylene oxide) (BPPO) substrate. The resulting
ZIF-8 membranes exhibited exceptional H2 permeance as high as
2.05 106 mol m2 s1 Pa1 with high H2/N2 and H2/CO2
selectivities (9.7 and 12.8, respectively).

Original language	English
Pages (from-to)	11474 - 11477
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	57
DOIs	https://doi.org/10.1039/c5cc03537f
Publication status	Published - 2015

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10.1039/c5cc03537f

3570547-AAM-oaAccepted author manuscript, 425 KB

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title = "Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support",

abstract = "Ultrathin ZIF-8 membranes with a thickness of around 200 nm were prepared by chemical vapour modification of surface chemistry and nanopores of an asymmetric bromomethylated poly(2,6- dimethyl-1,4-phenylene oxide) (BPPO) substrate. The resulting ZIF-8 membranes exhibited exceptional H2 permeance as high as 2.05 106 mol m2 s1 Pa1 with high H2/N2 and H2/CO2 selectivities (9.7 and 12.8, respectively).",

author = "Ezzatollah Shamsaei and Ze-Xian Low and Xiaocheng Lin and Alireza Mayahi and Huiyuan Liu and Xiwang Zhang and Liu, \{Jefferson Zhe\} and Huanting Wang",

year = "2015",

doi = "10.1039/c5cc03537f",

language = "English",

volume = "51",

pages = "11474 -- 11477",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "57",

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TY - JOUR

T1 - Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support

AU - Shamsaei, Ezzatollah

AU - Low, Ze-Xian

AU - Lin, Xiaocheng

AU - Mayahi, Alireza

AU - Liu, Huiyuan

AU - Zhang, Xiwang

AU - Liu, Jefferson Zhe

AU - Wang, Huanting

PY - 2015

Y1 - 2015

N2 - Ultrathin ZIF-8 membranes with a thickness of around 200 nm were prepared by chemical vapour modification of surface chemistry and nanopores of an asymmetric bromomethylated poly(2,6- dimethyl-1,4-phenylene oxide) (BPPO) substrate. The resulting ZIF-8 membranes exhibited exceptional H2 permeance as high as 2.05 106 mol m2 s1 Pa1 with high H2/N2 and H2/CO2 selectivities (9.7 and 12.8, respectively).

AB - Ultrathin ZIF-8 membranes with a thickness of around 200 nm were prepared by chemical vapour modification of surface chemistry and nanopores of an asymmetric bromomethylated poly(2,6- dimethyl-1,4-phenylene oxide) (BPPO) substrate. The resulting ZIF-8 membranes exhibited exceptional H2 permeance as high as 2.05 106 mol m2 s1 Pa1 with high H2/N2 and H2/CO2 selectivities (9.7 and 12.8, respectively).

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2015/cc/c5cc03537f

UR - https://www.scopus.com/pages/publications/84940516444

U2 - 10.1039/c5cc03537f

DO - 10.1039/c5cc03537f

M3 - Article

SN - 1359-7345

VL - 51

SP - 11474

EP - 11477

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support

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Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support

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