Rapid, metal-free hydrosilanisation chemistry for porous silicon surface modification

M J Sweetman, S. J P McInnes, R. B. Vasani, T. Guinan, A. Blencowe, N H Voelcker

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16 Citations (Scopus)

Abstract

Here, we report a novel surface modification for porous silicon (pSi). Hydroxyl-terminated pSi surfaces are modified with a hydrosilane via Si-H activation using the Lewis acid catalyst tris(pentafluorophenyl) borane. This surface reaction is fast and efficient at room temperature, and leads to a surface stabilised against hydrolytic attack in aqueous media. The resulting surface shows promise as a substrate for surface-assisted laser desorption/ionisation mass spectrometry.

Original languageEnglish
Pages (from-to)10640-10643
Number of pages4
JournalChemical Communications
Volume51
Issue number53
DOIs
Publication statusPublished - 7 Jul 2015
Externally publishedYes

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