Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an automated synthesizer

Joris J. Haven; Carlos Guerrero-Sanchez; Daniel J. Keddie; Graeme Moad

doi:10.1002/marc.201300459

Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an automated synthesizer

Joris J. Haven, Carlos Guerrero-Sanchez, Daniel J. Keddie, Graeme Moad

Research output: Contribution to journal › Article › Research › peer-review

40 Citations (Scopus)

Abstract

A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization. A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries by sequential RAFT polymerization in an automated synthesizer is reported.

Original language	English
Pages (from-to)	492-497
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	35
Issue number	4
DOIs	https://doi.org/10.1002/marc.201300459
Publication status	Published - 2014
Externally published	Yes

Keywords

automated parallel synthesizer
block copolymer
polymer library
sequential RAFT polymerization

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10.1002/marc.201300459

Cite this

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abstract = "A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization. A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries by sequential RAFT polymerization in an automated synthesizer is reported.",

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Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an automated synthesizer. / Haven, Joris J.; Guerrero-Sanchez, Carlos; Keddie, Daniel J. et al.
In: Macromolecular Rapid Communications, Vol. 35, No. 4, 2014, p. 492-497.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an automated synthesizer

AU - Haven, Joris J.

AU - Guerrero-Sanchez, Carlos

AU - Keddie, Daniel J.

AU - Moad, Graeme

PY - 2014

Y1 - 2014

N2 - A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization. A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries by sequential RAFT polymerization in an automated synthesizer is reported.

AB - A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization. A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries by sequential RAFT polymerization in an automated synthesizer is reported.

KW - automated parallel synthesizer

KW - block copolymer

KW - polymer library

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Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an automated synthesizer

Abstract

Keywords

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