Radicals and transition-metal catalysis: An alliance par excellence to increase reactivity and selectivity in organic chemistry

Leigh Ford; Ullrich Jahn

doi:10.1002/anie.200901761

Radicals and transition-metal catalysis: An alliance par excellence to increase reactivity and selectivity in organic chemistry

Leigh Ford, Ullrich Jahn

Research output: Contribution to journal › Article › Research › peer-review

48 Citations (Scopus)

Abstract

Welcome to radical catalysis: Radicals are tamed in transition-metal complexes which serve as catalysts for a number of reactions - Kumada couplings (see scheme), highly regioselective cobalt-catalyzed eliminations, Markovnikov additions, and reductive epoxide openings catalyzed by a titanium/rhodium system. All of these reactions are powered by the high reactivity of radical intermediates in the catalytic cycle of the metal-catalyzed process.

Original language	English
Pages (from-to)	6386 - 6389
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	35
DOIs	https://doi.org/10.1002/anie.200901761
Publication status	Published - 2009
Externally published	Yes

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10.1002/anie.200901761

Cite this

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title = "Radicals and transition-metal catalysis: An alliance par excellence to increase reactivity and selectivity in organic chemistry",

abstract = "Welcome to radical catalysis: Radicals are tamed in transition-metal complexes which serve as catalysts for a number of reactions - Kumada couplings (see scheme), highly regioselective cobalt-catalyzed eliminations, Markovnikov additions, and reductive epoxide openings catalyzed by a titanium/rhodium system. All of these reactions are powered by the high reactivity of radical intermediates in the catalytic cycle of the metal-catalyzed process.",

author = "Leigh Ford and Ullrich Jahn",

year = "2009",

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AU - Jahn, Ullrich

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AB - Welcome to radical catalysis: Radicals are tamed in transition-metal complexes which serve as catalysts for a number of reactions - Kumada couplings (see scheme), highly regioselective cobalt-catalyzed eliminations, Markovnikov additions, and reductive epoxide openings catalyzed by a titanium/rhodium system. All of these reactions are powered by the high reactivity of radical intermediates in the catalytic cycle of the metal-catalyzed process.

U2 - 10.1002/anie.200901761

DO - 10.1002/anie.200901761

M3 - Article

SN - 1433-7851

VL - 48

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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