@article{a53af734daaa487c8522e00b29acb4bb,
title = "Radical Coupling Initiated by Organophosphine Addition to Ynoates",
abstract = "Dual nucleophilic phosphine photoredox catalysis is yet to be developed due to facile oxidation of the phosphine organocatalyst to the phosphoranyl radical cation. Herein, we report a reaction design that avoids this event and exploits traditional nucleophilic phosphine organocatalysis with photoredox catalysis to allow the Giese coupling with ynoates. The approach has good generality, while its mechanism is supported by cyclic voltametric, Stern–Volmer quenching, and interception studies.",
keywords = "Dual Catalysis, Giese Reaction, Mechanistic Studies, Phosphine Organocatalysis, Photoredox Catalysis",
author = "Jing Cao and Antonia Seitz and Forni, \{Jos{\'e} A.\} and Anastasios Polyzos and Lupton, \{David W.\}",
note = "Funding Information: The authors thank the Australian Research Council through the Discovery (DP210103530) programs for financial support. Open Access publishing facilitated by Monash University, as part of the Wiley - Monash University agreement via the Council of Australian University Librarians. Funding Information: The authors thank the Australian Research Council through the Discovery (DP210103530) programs for financial support. Open Access publishing facilitated by Monash University, as part of the Wiley ‐ Monash University agreement via the Council of Australian University Librarians. Publisher Copyright: {\textcopyright} 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.",
year = "2023",
month = jul,
day = "17",
doi = "10.1002/anie.202303869",
language = "English",
volume = "62",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "Wiley-Blackwell",
number = "29",
}