Proton-functionalized graphitic carbon nitride for efficient metal-free destruction of escherichia coli under low-power light irradiation

Boon Junn Ng, Muhammad Khosyi Musyaffa, Chen Chen Er, Kulandai Arockia Rajesh Packiam, W. P.Cathie Lee, Lling Lling Tan, Hing Wah Lee, Chien Wei Ooi, Siang Piao Chai

Research output: Contribution to journalArticleResearchpeer-review

3 Citations (Scopus)

Abstract

Universal access to clean water has been a global ambition over the years. Photocatalytic water disinfection through advanced oxidation processes has been regarded as one of the promising methods for breaking down microbials. The forefront of this research focuses on the application of metal-free photocatalysts for disinfection to prevent secondary pollution. Graphitic carbon nitride (g-C3N4) has achieved instant attention as a metal-free and visible-light-responsive photocatalyst for various energy and environmental applications. However, the photocatalytic efficiency of g-C3N4 is still affected by its rapid charge recombination and sluggish electron-transfer kinetics. In this contribution, two-dimensionally protonated g-C3N4 was employed as metal-free photocatalyst for water treatment and demonstrated 100 % of Escherichia coli within 4 h under irradiation with a 23 W light bulb. The introduction of protonation can modulate the surface charge of g-C3N4; this enhances its conductivity and provides a “highway” for the delocalization of electrons. This work highlights the potential of conjugated polymers in antibacterial application.

Original languageEnglish
Pages (from-to)3085-3090
Number of pages6
JournalChemistry - A European Journal
Volume27
Issue number9
DOIs
Publication statusPublished - 10 Feb 2021

Keywords

  • anti-bacterial
  • graphitic carbon nitride
  • photocatalysis
  • protonation
  • water disinfection

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