Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques

Christopher Barner-Kowollik; Thomas P. Davis; Martina H. Stenzel

doi:10.1016/j.polymer.2004.09.017

Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques

Christopher Barner-Kowollik, Thomas P. Davis, Martina H. Stenzel

Research output: Contribution to journal › Article › Research › peer-review

115 Citations (Scopus)

Abstract

The present feature article provides an overview on the use of state-of-the-art mass spectrometry techniques such as matrix assisted laser desorption and ionization time of flight (MALDI-TOF) mass spectrometry as well as electrospray ionization mass spectrometry (ESI-MS) for probing the mechanism of free radical polymerization processes. The article features representative examples of the application of mass spectrometry techniques to conventional free radical polymerization, nitroxide mediated polymerization (NMP), atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer (RAFT) as well as catalytic chain transfer (CCT) processes.

Original language	English
Pages (from-to)	7791-7805
Number of pages	15
Journal	Polymer
Volume	45
Issue number	23
DOIs	https://doi.org/10.1016/j.polymer.2004.09.017
Publication status	Published - 1 Jan 2004
Externally published	Yes

Keywords

Electrospray ionization mass spectrometry
Free radical polymerization mechanism and kinetics
Matrix assisted laser desorption ionization-time of flight mass spectrometry

Access to Document

10.1016/j.polymer.2004.09.017

Cite this

@article{d73e2f2d0dca4476bdbc39b9514d7f3e,

title = "Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques",

abstract = "The present feature article provides an overview on the use of state-of-the-art mass spectrometry techniques such as matrix assisted laser desorption and ionization time of flight (MALDI-TOF) mass spectrometry as well as electrospray ionization mass spectrometry (ESI-MS) for probing the mechanism of free radical polymerization processes. The article features representative examples of the application of mass spectrometry techniques to conventional free radical polymerization, nitroxide mediated polymerization (NMP), atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer (RAFT) as well as catalytic chain transfer (CCT) processes.",

keywords = "Electrospray ionization mass spectrometry, Free radical polymerization mechanism and kinetics, Matrix assisted laser desorption ionization-time of flight mass spectrometry",

author = "Christopher Barner-Kowollik and Davis, {Thomas P.} and Stenzel, {Martina H.}",

year = "2004",

month = jan,

day = "1",

doi = "10.1016/j.polymer.2004.09.017",

language = "English",

volume = "45",

pages = "7791--7805",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier",

number = "23",

}

TY - JOUR

T1 - Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques

AU - Barner-Kowollik, Christopher

AU - Davis, Thomas P.

AU - Stenzel, Martina H.

PY - 2004/1/1

Y1 - 2004/1/1

N2 - The present feature article provides an overview on the use of state-of-the-art mass spectrometry techniques such as matrix assisted laser desorption and ionization time of flight (MALDI-TOF) mass spectrometry as well as electrospray ionization mass spectrometry (ESI-MS) for probing the mechanism of free radical polymerization processes. The article features representative examples of the application of mass spectrometry techniques to conventional free radical polymerization, nitroxide mediated polymerization (NMP), atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer (RAFT) as well as catalytic chain transfer (CCT) processes.

AB - The present feature article provides an overview on the use of state-of-the-art mass spectrometry techniques such as matrix assisted laser desorption and ionization time of flight (MALDI-TOF) mass spectrometry as well as electrospray ionization mass spectrometry (ESI-MS) for probing the mechanism of free radical polymerization processes. The article features representative examples of the application of mass spectrometry techniques to conventional free radical polymerization, nitroxide mediated polymerization (NMP), atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer (RAFT) as well as catalytic chain transfer (CCT) processes.

KW - Electrospray ionization mass spectrometry

KW - Free radical polymerization mechanism and kinetics

KW - Matrix assisted laser desorption ionization-time of flight mass spectrometry

UR - http://www.scopus.com/inward/record.url?scp=5644302153&partnerID=8YFLogxK

U2 - 10.1016/j.polymer.2004.09.017

DO - 10.1016/j.polymer.2004.09.017

M3 - Article

AN - SCOPUS:5644302153

SN - 0032-3861

VL - 45

SP - 7791

EP - 7805

JO - Polymer

JF - Polymer

IS - 23

ER -

Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques

Abstract

Keywords

Access to Document

Other files and links

Cite this