Preparation of hybrid films containing gold nanoparticles and cobalt porphyrin with flexible electrochemical properties

Yan Shen; Fang Zhan; Jianfeng Lu; Bingyan Zhang; Dekang Kang Huang; Xiaobao Xu; Yibo Zhang; Mingkui Wang

doi:10.1016/j.tsf.2013.08.002

Preparation of hybrid films containing gold nanoparticles and cobalt porphyrin with flexible electrochemical properties

Yan Shen, Fang Zhan, Jianfeng Lu, Bingyan Zhang, Dekang Kang Huang, Xiaobao Xu, Yibo Zhang, Mingkui Wang

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

We report on the fabrication of hybrid films of gold nanoparticles (AuNPs) and [tetrakis (N-methylpyridyl)porphyrinato] cobalt (CoTMPyP) based on electrostatic layer-by-layer (LBL) self-assembly technique.A three-dimensional nanostructured film composed of positively charged CoTMPyP and negatively charged poly(acrylic acid)-stabilized AuNPs can be formed onto various substrates, including 4-aminobenzoic acid modified glassy carbon electrode, 11-mercaptotroponic acid modified gold film, and quartz plate with negatively charged surface.The regular growth of hybrid films is investigated by UV-vis spectroscopy, surface plasma resonance, and impedance spectroscopy.The prepared multilayer films possess flexible electro-catalytic activity toward O ₂ reduction reaction.It is noted that the electro-catalytic capability of the prepared multilayer film decreases as bilayer number increases.The unexpected observation of catalytic activity with bilayer number is investigated in detail.

Original language	English
Pages (from-to)	327-331
Number of pages	5
Journal	Thin Solid Films
Volume	545
DOIs	https://doi.org/10.1016/j.tsf.2013.08.002
Publication status	Published - 31 Oct 2013
Externally published	Yes

Keywords

Au nanoparticles
Cobalt porphyrin
Layer-by-layer self-assembly
Oxygen reduction

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10.1016/j.tsf.2013.08.002

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@article{94b3b242cbe64049ba361a56825ef66f,

title = "Preparation of hybrid films containing gold nanoparticles and cobalt porphyrin with flexible electrochemical properties",

abstract = "We report on the fabrication of hybrid films of gold nanoparticles (AuNPs) and [tetrakis (N-methylpyridyl)porphyrinato] cobalt (CoTMPyP) based on electrostatic layer-by-layer (LBL) self-assembly technique.A three-dimensional nanostructured film composed of positively charged CoTMPyP and negatively charged poly(acrylic acid)-stabilized AuNPs can be formed onto various substrates, including 4-aminobenzoic acid modified glassy carbon electrode, 11-mercaptotroponic acid modified gold film, and quartz plate with negatively charged surface.The regular growth of hybrid films is investigated by UV-vis spectroscopy, surface plasma resonance, and impedance spectroscopy.The prepared multilayer films possess flexible electro-catalytic activity toward O 2 reduction reaction.It is noted that the electro-catalytic capability of the prepared multilayer film decreases as bilayer number increases.The unexpected observation of catalytic activity with bilayer number is investigated in detail.",

keywords = "Au nanoparticles, Cobalt porphyrin, Layer-by-layer self-assembly, Oxygen reduction",

author = "Yan Shen and Fang Zhan and Jianfeng Lu and Bingyan Zhang and Huang, {Dekang Kang} and Xiaobao Xu and Yibo Zhang and Mingkui Wang",

year = "2013",

month = oct,

day = "31",

doi = "10.1016/j.tsf.2013.08.002",

language = "English",

volume = "545",

pages = "327--331",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier",

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TY - JOUR

T1 - Preparation of hybrid films containing gold nanoparticles and cobalt porphyrin with flexible electrochemical properties

AU - Shen, Yan

AU - Zhan, Fang

AU - Lu, Jianfeng

AU - Zhang, Bingyan

AU - Huang, Dekang Kang

AU - Xu, Xiaobao

AU - Zhang, Yibo

AU - Wang, Mingkui

PY - 2013/10/31

Y1 - 2013/10/31

N2 - We report on the fabrication of hybrid films of gold nanoparticles (AuNPs) and [tetrakis (N-methylpyridyl)porphyrinato] cobalt (CoTMPyP) based on electrostatic layer-by-layer (LBL) self-assembly technique.A three-dimensional nanostructured film composed of positively charged CoTMPyP and negatively charged poly(acrylic acid)-stabilized AuNPs can be formed onto various substrates, including 4-aminobenzoic acid modified glassy carbon electrode, 11-mercaptotroponic acid modified gold film, and quartz plate with negatively charged surface.The regular growth of hybrid films is investigated by UV-vis spectroscopy, surface plasma resonance, and impedance spectroscopy.The prepared multilayer films possess flexible electro-catalytic activity toward O 2 reduction reaction.It is noted that the electro-catalytic capability of the prepared multilayer film decreases as bilayer number increases.The unexpected observation of catalytic activity with bilayer number is investigated in detail.

AB - We report on the fabrication of hybrid films of gold nanoparticles (AuNPs) and [tetrakis (N-methylpyridyl)porphyrinato] cobalt (CoTMPyP) based on electrostatic layer-by-layer (LBL) self-assembly technique.A three-dimensional nanostructured film composed of positively charged CoTMPyP and negatively charged poly(acrylic acid)-stabilized AuNPs can be formed onto various substrates, including 4-aminobenzoic acid modified glassy carbon electrode, 11-mercaptotroponic acid modified gold film, and quartz plate with negatively charged surface.The regular growth of hybrid films is investigated by UV-vis spectroscopy, surface plasma resonance, and impedance spectroscopy.The prepared multilayer films possess flexible electro-catalytic activity toward O 2 reduction reaction.It is noted that the electro-catalytic capability of the prepared multilayer film decreases as bilayer number increases.The unexpected observation of catalytic activity with bilayer number is investigated in detail.

KW - Au nanoparticles

KW - Cobalt porphyrin

KW - Layer-by-layer self-assembly

KW - Oxygen reduction

UR - http://www.scopus.com/inward/record.url?scp=84884981041&partnerID=8YFLogxK

U2 - 10.1016/j.tsf.2013.08.002

DO - 10.1016/j.tsf.2013.08.002

M3 - Article

AN - SCOPUS:84884981041

VL - 545

SP - 327

EP - 331

JO - Thin Solid Films

JF - Thin Solid Films

SN - 0040-6090

ER -

Preparation of hybrid films containing gold nanoparticles and cobalt porphyrin with flexible electrochemical properties

Abstract

Keywords

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