Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives

Katharine A. Smith; Glen B. Deacon; W. Roy Jackson; Jack Miller

Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives

Katharine A. Smith, Glen B. Deacon, W. Roy Jackson, Jack Miller

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

The bimetallics [PhBi(Ox)₂(NaX)_n] (Ox^- = quinolin-8-olate: X = Cl, Br or I), containing variable amounts of sodium halides, have been prepared by reaction of PhBiX₂ with Na(Ox) (mole ratio 1:2) or of Ph₂BiX with Na(Ox) (mole ratio 1:1) in ethanol. A similar preparation has given [PhBi(MeOx)₂(NaI)_n] (MeOx^- = 2-methylquinolin-8-olate). The bimetallics have been characterized by X-ray powder photography, f.a.b. mass spectrometry and ¹H n.m.r. and electronic spectroscopy. Sodium halide-free PhBi(Ox)₂ was obtained from the reaction of Ph₂BiCl with Na(Ox) in the presence of 15-crown-5, or from treatment of PhBiI₂ or Ph₂BiI with NBu₄(Ox). Reaction of equimolar amounts of PhBiI₂ and Na(Ox) gives Bi(Ox)₂I. which can also be obtained from BiI₃ and Na(Ox) in a 1:1 or 1:2 stoichiometry. Treatment of PhBiI₂ with M(Ox) (M = Na or K) in a 1:3 mole ratio yields [MPhBi(Ox)₃] bimetallics, which appear to contain both chelating and unidentate Ox ligands from their electronic spectra.

Original language	English
Pages (from-to)	231-238
Number of pages	8
Journal	Australian Journal of Chemistry
Volume	49
Issue number	2
Publication status	Published - 1996

Cite this

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title = "Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives",

abstract = "The bimetallics [PhBi(Ox)2(NaX)n] (Ox- = quinolin-8-olate: X = Cl, Br or I), containing variable amounts of sodium halides, have been prepared by reaction of PhBiX2 with Na(Ox) (mole ratio 1:2) or of Ph2BiX with Na(Ox) (mole ratio 1:1) in ethanol. A similar preparation has given [PhBi(MeOx)2(NaI)n] (MeOx- = 2-methylquinolin-8-olate). The bimetallics have been characterized by X-ray powder photography, f.a.b. mass spectrometry and 1H n.m.r. and electronic spectroscopy. Sodium halide-free PhBi(Ox)2 was obtained from the reaction of Ph2BiCl with Na(Ox) in the presence of 15-crown-5, or from treatment of PhBiI2 or Ph2BiI with NBu4(Ox). Reaction of equimolar amounts of PhBiI2 and Na(Ox) gives Bi(Ox)2I. which can also be obtained from BiI3 and Na(Ox) in a 1:1 or 1:2 stoichiometry. Treatment of PhBiI2 with M(Ox) (M = Na or K) in a 1:3 mole ratio yields [MPhBi(Ox)3] bimetallics, which appear to contain both chelating and unidentate Ox ligands from their electronic spectra.",

author = "Smith, {Katharine A.} and Deacon, {Glen B.} and Jackson, {W. Roy} and Jack Miller",

year = "1996",

language = "English",

volume = "49",

pages = "231--238",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "2",

}

TY - JOUR

T1 - Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives

AU - Smith, Katharine A.

AU - Deacon, Glen B.

AU - Jackson, W. Roy

AU - Miller, Jack

PY - 1996

Y1 - 1996

N2 - The bimetallics [PhBi(Ox)2(NaX)n] (Ox- = quinolin-8-olate: X = Cl, Br or I), containing variable amounts of sodium halides, have been prepared by reaction of PhBiX2 with Na(Ox) (mole ratio 1:2) or of Ph2BiX with Na(Ox) (mole ratio 1:1) in ethanol. A similar preparation has given [PhBi(MeOx)2(NaI)n] (MeOx- = 2-methylquinolin-8-olate). The bimetallics have been characterized by X-ray powder photography, f.a.b. mass spectrometry and 1H n.m.r. and electronic spectroscopy. Sodium halide-free PhBi(Ox)2 was obtained from the reaction of Ph2BiCl with Na(Ox) in the presence of 15-crown-5, or from treatment of PhBiI2 or Ph2BiI with NBu4(Ox). Reaction of equimolar amounts of PhBiI2 and Na(Ox) gives Bi(Ox)2I. which can also be obtained from BiI3 and Na(Ox) in a 1:1 or 1:2 stoichiometry. Treatment of PhBiI2 with M(Ox) (M = Na or K) in a 1:3 mole ratio yields [MPhBi(Ox)3] bimetallics, which appear to contain both chelating and unidentate Ox ligands from their electronic spectra.

AB - The bimetallics [PhBi(Ox)2(NaX)n] (Ox- = quinolin-8-olate: X = Cl, Br or I), containing variable amounts of sodium halides, have been prepared by reaction of PhBiX2 with Na(Ox) (mole ratio 1:2) or of Ph2BiX with Na(Ox) (mole ratio 1:1) in ethanol. A similar preparation has given [PhBi(MeOx)2(NaI)n] (MeOx- = 2-methylquinolin-8-olate). The bimetallics have been characterized by X-ray powder photography, f.a.b. mass spectrometry and 1H n.m.r. and electronic spectroscopy. Sodium halide-free PhBi(Ox)2 was obtained from the reaction of Ph2BiCl with Na(Ox) in the presence of 15-crown-5, or from treatment of PhBiI2 or Ph2BiI with NBu4(Ox). Reaction of equimolar amounts of PhBiI2 and Na(Ox) gives Bi(Ox)2I. which can also be obtained from BiI3 and Na(Ox) in a 1:1 or 1:2 stoichiometry. Treatment of PhBiI2 with M(Ox) (M = Na or K) in a 1:3 mole ratio yields [MPhBi(Ox)3] bimetallics, which appear to contain both chelating and unidentate Ox ligands from their electronic spectra.

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M3 - Article

AN - SCOPUS:7444225219

SN - 0004-9425

VL - 49

SP - 231

EP - 238

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 2

ER -

Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives

Abstract

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