Preparation and characterization of a water soluble methylated β-cyclodextrin/camphorquinone complex

Jing Zhang, Pu Xiao, Suqing Shi, Jun Nie

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9 Citations (Scopus)

Abstract

A water soluble methylated β-cyclodextrin/camphorquinone (MCD/CQ) complex, based on methylated β-cyclodextrin (MCD) and camphorquinone (CQ), was prepared and its structure was characterized by FTIR, 1H-NMR, and UV-vis spectra. The photopolymerization kinetics of MCD/CQ in the water soluble monomer system was studied by Real-time Infrared spectroscopy (RT-IR). Compared to the photopolymerization carried out under nearly identical conditions but without MCD, the polymerization rate and final conversion initiated by a CQ-triethanolamine photoinitiator system were slightly lower. The effects of different MCD/CQ concentration, triethanolamine concentration, and light intensity were also studied.

Original languageEnglish
Pages (from-to)723-728
Number of pages6
JournalPolymers for Advanced Technologies
Volume20
Issue number9
DOIs
Publication statusPublished - 2009
Externally publishedYes

Keywords

  • Camphorquinone
  • Cyclodextrin
  • Kinetics
  • RT-IR
  • Water soluble photoinitiator

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