Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

Cyrille Boyer; Alexander H Soeriyadi; Peter J Roth; Michael Raymond Whittaker; Thomas Paul Davis

doi:10.1039/c0cc03815f

Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

Cyrille Boyer, Alexander H Soeriyadi, Peter J Roth, Michael Raymond Whittaker, Thomas Paul Davis

Research output: Contribution to journal › Article › Research › peer-review

57 Citations (Scopus)

Abstract

In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene click reactions.

Original language	English
Pages (from-to)	1318 - 1320
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	4
DOIs	https://doi.org/10.1039/c0cc03815f
Publication status	Published - 2011
Externally published	Yes

Access to Document

10.1039/c0cc03815f

Cite this

@article{256c31b245cd44ec8aececa840b35b71,

title = "Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry",

abstract = "In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene click reactions.",

author = "Cyrille Boyer and Soeriyadi, \{Alexander H\} and Roth, \{Peter J\} and Whittaker, \{Michael Raymond\} and Davis, \{Thomas Paul\}",

year = "2011",

doi = "10.1039/c0cc03815f",

language = "English",

volume = "47",

pages = "1318 -- 1320",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

AU - Boyer, Cyrille

AU - Soeriyadi, Alexander H

AU - Roth, Peter J

AU - Whittaker, Michael Raymond

AU - Davis, Thomas Paul

PY - 2011

Y1 - 2011

N2 - In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene click reactions.

AB - In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene click reactions.

UR - https://www.scopus.com/pages/publications/78651273635

U2 - 10.1039/c0cc03815f

DO - 10.1039/c0cc03815f

M3 - Article

SN - 1359-7345

VL - 47

SP - 1318

EP - 1320

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry

Abstract

Access to Document

Other files and links

Cite this