Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi2O3 under mild conditions

Dimuthu Senevirathna; Victoria Blair; Melissa Werrett; Philip Andrews

doi:10.1021/acs.inorgchem.6b01937

Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi₂O₃ under mild conditions

Dimuthu Senevirathna, Victoria Blair, Melissa Werrett, Philip Andrews

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

Eight novel bismuth(III) sulfonato compounds have been synthesized and characterized using the sonochemical reaction of Bi₂O₃ with a range of sulfonic acids, including 2,5-dimethylbenzenesulfonic acid (2,5-DMSH), 2,4-dinitrobenzenesulfonic acid (2,4-DNSH), 2,5-dichlorobenzenesulfonic acid (2,5-DCSH), 1,2-benzenedisulfonic acid (1,2-BDSH₂), 1,3-benzenedisulfonic acid (1,3-BDSH₂), 2-sulfobenzoic acid (2-SBH₂), 3-sulfobenzoic acid (3-SBH₂), and 2-naphthalenesulfonic acid (NPSH). Six of the complexes (1, 2, 4, and 6-8) were structurally characterized through single-crystal X-ray crystallography. In the presence of the monosulfonic acids 2,5-DMSH, 2,4-DNSH, and 2,5-DCSH, polynuclear bismuth(III) oxido clusters were isolated: namely, [Bi₆O₄(OH)₄(2,5-DMS)₆(H₂O)₆]·10H₂O (1·10H₂O), [Bi₆O₄(OH)₄(2,4-DNS)₆(H₂O)₆]·6H₂O (2·6H₂O), and [Bi₆O₄(OH)₄(2,5-DCS)₆(H₂O)₆] (3). The disulfonic acid 1,3-BDSH₂ also produced an oxido cluster: [Bi₆O₄(OH)₄(1,3-BDS)₃]·8H₂O (5·8H₂O). The remaining diacid ligands (1,2-BDSH₂, 2-SBH₂, and 3-SBH₂), upon reaction with Bi₂O₃, produced polymeric Bi(III) sulfonato complexes: namely [Bi(1,2-BDS)(OH)(H₂O)₂]_∞ (4), [Bi(2-SB)(2-SBH)H₂O]_∞·2H₂O (6·2H₂O), and [NH₂(Me)₂]₂[Bi₂(3-SB)₄]_∞ (7). The larger NPSH ligand produced the monomeric contact ion pair [Bi(NPS)₂(H₂O)₆][NPS]·3H₂O (8·3H₂O), upon sonication with Bi₂O₃.

Original language	English
Pages (from-to)	11426-11433
Number of pages	8
Journal	Inorganic Chemistry
Volume	55
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01937
Publication status	Published - 7 Nov 2016

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@article{0af84886164d49c38fb7327ef939d0b8,

title = "Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi2O3 under mild conditions",

abstract = "Eight novel bismuth(III) sulfonato compounds have been synthesized and characterized using the sonochemical reaction of Bi2O3 with a range of sulfonic acids, including 2,5-dimethylbenzenesulfonic acid (2,5-DMSH), 2,4-dinitrobenzenesulfonic acid (2,4-DNSH), 2,5-dichlorobenzenesulfonic acid (2,5-DCSH), 1,2-benzenedisulfonic acid (1,2-BDSH2), 1,3-benzenedisulfonic acid (1,3-BDSH2), 2-sulfobenzoic acid (2-SBH2), 3-sulfobenzoic acid (3-SBH2), and 2-naphthalenesulfonic acid (NPSH). Six of the complexes (1, 2, 4, and 6-8) were structurally characterized through single-crystal X-ray crystallography. In the presence of the monosulfonic acids 2,5-DMSH, 2,4-DNSH, and 2,5-DCSH, polynuclear bismuth(III) oxido clusters were isolated: namely, [Bi6O4(OH)4(2,5-DMS)6(H2O)6]·10H2O (1·10H2O), [Bi6O4(OH)4(2,4-DNS)6(H2O)6]·6H2O (2·6H2O), and [Bi6O4(OH)4(2,5-DCS)6(H2O)6] (3). The disulfonic acid 1,3-BDSH2 also produced an oxido cluster: [Bi6O4(OH)4(1,3-BDS)3]·8H2O (5·8H2O). The remaining diacid ligands (1,2-BDSH2, 2-SBH2, and 3-SBH2), upon reaction with Bi2O3, produced polymeric Bi(III) sulfonato complexes: namely [Bi(1,2-BDS)(OH)(H2O)2]∞ (4), [Bi(2-SB)(2-SBH)H2O]∞·2H2O (6·2H2O), and [NH2(Me)2]2[Bi2(3-SB)4]∞ (7). The larger NPSH ligand produced the monomeric contact ion pair [Bi(NPS)2(H2O)6][NPS]·3H2O (8·3H2O), upon sonication with Bi2O3.",

author = "Dimuthu Senevirathna and Victoria Blair and Melissa Werrett and Philip Andrews",

year = "2016",

month = nov,

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doi = "10.1021/acs.inorgchem.6b01937",

language = "English",

volume = "55",

pages = "11426--11433",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi2O3 under mild conditions

AU - Senevirathna, Dimuthu

AU - Blair, Victoria

AU - Werrett, Melissa

AU - Andrews, Philip

PY - 2016/11/7

Y1 - 2016/11/7

N2 - Eight novel bismuth(III) sulfonato compounds have been synthesized and characterized using the sonochemical reaction of Bi2O3 with a range of sulfonic acids, including 2,5-dimethylbenzenesulfonic acid (2,5-DMSH), 2,4-dinitrobenzenesulfonic acid (2,4-DNSH), 2,5-dichlorobenzenesulfonic acid (2,5-DCSH), 1,2-benzenedisulfonic acid (1,2-BDSH2), 1,3-benzenedisulfonic acid (1,3-BDSH2), 2-sulfobenzoic acid (2-SBH2), 3-sulfobenzoic acid (3-SBH2), and 2-naphthalenesulfonic acid (NPSH). Six of the complexes (1, 2, 4, and 6-8) were structurally characterized through single-crystal X-ray crystallography. In the presence of the monosulfonic acids 2,5-DMSH, 2,4-DNSH, and 2,5-DCSH, polynuclear bismuth(III) oxido clusters were isolated: namely, [Bi6O4(OH)4(2,5-DMS)6(H2O)6]·10H2O (1·10H2O), [Bi6O4(OH)4(2,4-DNS)6(H2O)6]·6H2O (2·6H2O), and [Bi6O4(OH)4(2,5-DCS)6(H2O)6] (3). The disulfonic acid 1,3-BDSH2 also produced an oxido cluster: [Bi6O4(OH)4(1,3-BDS)3]·8H2O (5·8H2O). The remaining diacid ligands (1,2-BDSH2, 2-SBH2, and 3-SBH2), upon reaction with Bi2O3, produced polymeric Bi(III) sulfonato complexes: namely [Bi(1,2-BDS)(OH)(H2O)2]∞ (4), [Bi(2-SB)(2-SBH)H2O]∞·2H2O (6·2H2O), and [NH2(Me)2]2[Bi2(3-SB)4]∞ (7). The larger NPSH ligand produced the monomeric contact ion pair [Bi(NPS)2(H2O)6][NPS]·3H2O (8·3H2O), upon sonication with Bi2O3.

AB - Eight novel bismuth(III) sulfonato compounds have been synthesized and characterized using the sonochemical reaction of Bi2O3 with a range of sulfonic acids, including 2,5-dimethylbenzenesulfonic acid (2,5-DMSH), 2,4-dinitrobenzenesulfonic acid (2,4-DNSH), 2,5-dichlorobenzenesulfonic acid (2,5-DCSH), 1,2-benzenedisulfonic acid (1,2-BDSH2), 1,3-benzenedisulfonic acid (1,3-BDSH2), 2-sulfobenzoic acid (2-SBH2), 3-sulfobenzoic acid (3-SBH2), and 2-naphthalenesulfonic acid (NPSH). Six of the complexes (1, 2, 4, and 6-8) were structurally characterized through single-crystal X-ray crystallography. In the presence of the monosulfonic acids 2,5-DMSH, 2,4-DNSH, and 2,5-DCSH, polynuclear bismuth(III) oxido clusters were isolated: namely, [Bi6O4(OH)4(2,5-DMS)6(H2O)6]·10H2O (1·10H2O), [Bi6O4(OH)4(2,4-DNS)6(H2O)6]·6H2O (2·6H2O), and [Bi6O4(OH)4(2,5-DCS)6(H2O)6] (3). The disulfonic acid 1,3-BDSH2 also produced an oxido cluster: [Bi6O4(OH)4(1,3-BDS)3]·8H2O (5·8H2O). The remaining diacid ligands (1,2-BDSH2, 2-SBH2, and 3-SBH2), upon reaction with Bi2O3, produced polymeric Bi(III) sulfonato complexes: namely [Bi(1,2-BDS)(OH)(H2O)2]∞ (4), [Bi(2-SB)(2-SBH)H2O]∞·2H2O (6·2H2O), and [NH2(Me)2]2[Bi2(3-SB)4]∞ (7). The larger NPSH ligand produced the monomeric contact ion pair [Bi(NPS)2(H2O)6][NPS]·3H2O (8·3H2O), upon sonication with Bi2O3.

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U2 - 10.1021/acs.inorgchem.6b01937

DO - 10.1021/acs.inorgchem.6b01937

M3 - Article

AN - SCOPUS:84994645473

VL - 55

SP - 11426

EP - 11433

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 21

ER -

Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi₂O₃ under mild conditions

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Targeting Bio-Compatible Homo- and Hetero-bimetallic Cages and their Application in High Energy and Dual Energy Computed Tomography

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Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi2O3 under mild conditions

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Targeting Bio-Compatible Homo- and Hetero-bimetallic Cages and their Application in High Energy and Dual Energy Computed Tomography

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Polynuclear bismuth oxido sulfonato clusters, polymers, and ion pairs from Bi₂O₃ under mild conditions