Poly(norbornyl-NDIs) as a potential cathode-active material in rechargeable charge storage devices

Y. Sasada; S. J. Langford; Kenichi Oyaizu; Hiroyuki Nishide

doi:10.1039/c6ra06103f

Poly(norbornyl-NDIs) as a potential cathode-active material in rechargeable charge storage devices

Y. Sasada
, S. J. Langford
, Kenichi Oyaizu
, Hiroyuki Nishide

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

Two pendant-type naphthalene diimide (NDI) polymers bearing a polynorbornene backbone were prepared and their electrochemical properties explored. The NDI-based polymers displayed reversible redox responses in 1 M LiClO₄ γ-butyrolactone electrolyte. Polymer 1, bearing a N-methyl group, exhibited remarkable charge-storage capabilities which demonstrated its potential usefulness as an organic cathode-active material in rechargeable devices with excellent performances such as large charge capacity, high rate capability, and charge-discharge cyclability.

Original language	English
Pages (from-to)	42911-42916
Number of pages	6
Journal	RSC Advances
Volume	6
Issue number	49
DOIs	https://doi.org/10.1039/c6ra06103f
Publication status	Published - 2016

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10.1039/c6ra06103f

39899568-oaAccepted author manuscript, 865 KB

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AU - Sasada, Y.

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AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

PY - 2016

Y1 - 2016

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AB - Two pendant-type naphthalene diimide (NDI) polymers bearing a polynorbornene backbone were prepared and their electrochemical properties explored. The NDI-based polymers displayed reversible redox responses in 1 M LiClO4 γ-butyrolactone electrolyte. Polymer 1, bearing a N-methyl group, exhibited remarkable charge-storage capabilities which demonstrated its potential usefulness as an organic cathode-active material in rechargeable devices with excellent performances such as large charge capacity, high rate capability, and charge-discharge cyclability.

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Poly(norbornyl-NDIs) as a potential cathode-active material in rechargeable charge storage devices

Abstract

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New Generation Functional Materials for 21st Century Applications - Exploiting the Properties of Naphthalene Diimides

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Poly(norbornyl-NDIs) as a potential cathode-active material in rechargeable charge storage devices

Abstract

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New Generation Functional Materials for 21st Century Applications - Exploiting the Properties of Naphthalene Diimides

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