Polymer-supported molybdenyl thioglycolate as oxygen atom transfer reagent

Pau Arroyo; Salvador Gil; Amalia Muñoz; Pedro Palanca; Joaquin Sanchis; Vicent Sanz

doi:10.1016/S1381-1169(00)00271-5

Polymer-supported molybdenyl thioglycolate as oxygen atom transfer reagent

Pau Arroyo, Salvador Gil, Amalia Muñoz, Pedro Palanca, Joaquin Sanchis, Vicent Sanz

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

Oxo-transfer reactions of a variety of substrates in DMF or methanol using polymer-supported molybdenyl thioglycolate (PSMT) have been investigated. The clean oxidation of Me₂PhP, n-butanethiol or benzoin to yield Me₂PhPO, disulfide or benzil, respectively, occurs in high yield. In the presence of air or pyridine N-oxide, a catalytic cycle is accomplished which goes on until the completion of the substrate.

Original language	English
Pages (from-to)	403-408
Number of pages	6
Journal	Journal of Molecular Catalysis A: Chemical
Volume	160
Issue number	2
DOIs	https://doi.org/10.1016/S1381-1169(00)00271-5
Publication status	Published - 31 Oct 2000
Externally published	Yes

Keywords

Air oxidation
Heterogeneous catalyst
Molybdenum

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10.1016/S1381-1169(00)00271-5

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abstract = "Oxo-transfer reactions of a variety of substrates in DMF or methanol using polymer-supported molybdenyl thioglycolate (PSMT) have been investigated. The clean oxidation of Me2PhP, n-butanethiol or benzoin to yield Me2PhPO, disulfide or benzil, respectively, occurs in high yield. In the presence of air or pyridine N-oxide, a catalytic cycle is accomplished which goes on until the completion of the substrate.",

keywords = "Air oxidation, Heterogeneous catalyst, Molybdenum",

author = "Pau Arroyo and Salvador Gil and Amalia Mu{\~n}oz and Pedro Palanca and Joaquin Sanchis and Vicent Sanz",

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T1 - Polymer-supported molybdenyl thioglycolate as oxygen atom transfer reagent

AU - Arroyo, Pau

AU - Gil, Salvador

AU - Muñoz, Amalia

AU - Palanca, Pedro

AU - Sanchis, Joaquin

AU - Sanz, Vicent

PY - 2000/10/31

Y1 - 2000/10/31

N2 - Oxo-transfer reactions of a variety of substrates in DMF or methanol using polymer-supported molybdenyl thioglycolate (PSMT) have been investigated. The clean oxidation of Me2PhP, n-butanethiol or benzoin to yield Me2PhPO, disulfide or benzil, respectively, occurs in high yield. In the presence of air or pyridine N-oxide, a catalytic cycle is accomplished which goes on until the completion of the substrate.

AB - Oxo-transfer reactions of a variety of substrates in DMF or methanol using polymer-supported molybdenyl thioglycolate (PSMT) have been investigated. The clean oxidation of Me2PhP, n-butanethiol or benzoin to yield Me2PhPO, disulfide or benzil, respectively, occurs in high yield. In the presence of air or pyridine N-oxide, a catalytic cycle is accomplished which goes on until the completion of the substrate.

KW - Air oxidation

KW - Heterogeneous catalyst

KW - Molybdenum

UR - http://www.scopus.com/inward/record.url?scp=0034739606&partnerID=8YFLogxK

U2 - 10.1016/S1381-1169(00)00271-5

DO - 10.1016/S1381-1169(00)00271-5

M3 - Article

AN - SCOPUS:0034739606

SN - 1381-1169

VL - 160

SP - 403

EP - 408

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 2

ER -

Polymer-supported molybdenyl thioglycolate as oxygen atom transfer reagent

Abstract

Keywords

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