Poly(N-4-vinylbenzyl-1,4,7-triazacyclononane) copper complex grafted solid catalyst for oxidative polymerization of 2,6-dimethylphenol

Kei Saito, Koji Miyamoto, Sepa Nanayakkara, Hirotaka Ihara, Milton Hearn

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A new solid phase catalyst, poly(N-4-vinylbenzyl-1,4,7-triazacyclononane) copper(I) complex, grafted onto polystyrene particles, has been employed for the oxidative polymerization of 2,6-dimethylphenol using an aqueous biphasic (water/toluene) solvent system. The solid catalyst was synthesized by first grafting N-(4-vinylbenzyl)-1,4,7-triaza-cyclononane onto polystyrene particles using a radical mediated polymerization method and next by creating the polymer-metal complex of copper-triazacyclononane with these modified particles. Poly(2,6-dimethyl-1,4-phenylene oxide) was successfully obtained from the polymerization of 2,6-dimethylphenol using this new metal-organic solid phase catalyst.

Original languageEnglish
Article number146
Number of pages7
Issue number2
Publication statusPublished - 1 Feb 2016


  • Macromolecular metal complexes
  • Oxidative polymerization
  • Solid catalysts

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