Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes

Jiazeng Sun; D. R. Macfarlane; M. Forsyth

doi:10.1016/0013-4686(95)00182-E

Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes

Jiazeng Sun, D. R. Macfarlane, M. Forsyth

Research output: Contribution to journal › Article › Research › peer-review

24 Citations (Scopus)

Abstract

Methoxy-ethylene glycol methacrylates, CH₂CMeCOO(CH₂CH₂O)_nMe (n = 1, 2, 3), ethoxy-triethylene glycol methacrylate, CH₂CMeCOO(CH₂CH₂O)₃Et, and N,N-dimethylaminoethyl methacrylate, CH₂CMeCOOCH₂CH₂NMe₂, were used to synthesise the corresponding polymers. Conductivities of these polymers complexed with lithium perchlorate were investigated. Tetraethylene glycol dimethyl ether was used as plasticiser to increase the conductivity of the materials. A conductivity of 10^-5 S cm^-1 was obtained at room temperature for the plasticised polymer samples. Effects of polymer structure, plasticiser, salt concentration and temperature on conductivity and glass transition temperature of the polymer electrolytes are discussed.

Original language	English
Pages (from-to)	2301-2304
Number of pages	4
Journal	Electrochimica Acta
Volume	40
Issue number	13-14
DOIs	https://doi.org/10.1016/0013-4686(95)00182-E
Publication status	Published - 1 Jan 1995

Keywords

glass transition temperature
ionic conductivity
lithium perchlorate
plasticiser
poly(ethylene glycol methacrylate)
polymer electrolyte

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10.1016/0013-4686(95)00182-E

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title = "Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes",

abstract = "Methoxy-ethylene glycol methacrylates, CH2CMeCOO(CH2CH2O)nMe (n = 1, 2, 3), ethoxy-triethylene glycol methacrylate, CH2CMeCOO(CH2CH2O)3Et, and N,N-dimethylaminoethyl methacrylate, CH2CMeCOOCH2CH2NMe2, were used to synthesise the corresponding polymers. Conductivities of these polymers complexed with lithium perchlorate were investigated. Tetraethylene glycol dimethyl ether was used as plasticiser to increase the conductivity of the materials. A conductivity of 10-5 S cm-1 was obtained at room temperature for the plasticised polymer samples. Effects of polymer structure, plasticiser, salt concentration and temperature on conductivity and glass transition temperature of the polymer electrolytes are discussed.",

keywords = "glass transition temperature, ionic conductivity, lithium perchlorate, plasticiser, poly(ethylene glycol methacrylate), polymer electrolyte",

author = "Jiazeng Sun and Macfarlane, {D. R.} and M. Forsyth",

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TY - JOUR

T1 - Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes

AU - Sun, Jiazeng

AU - Macfarlane, D. R.

AU - Forsyth, M.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Methoxy-ethylene glycol methacrylates, CH2CMeCOO(CH2CH2O)nMe (n = 1, 2, 3), ethoxy-triethylene glycol methacrylate, CH2CMeCOO(CH2CH2O)3Et, and N,N-dimethylaminoethyl methacrylate, CH2CMeCOOCH2CH2NMe2, were used to synthesise the corresponding polymers. Conductivities of these polymers complexed with lithium perchlorate were investigated. Tetraethylene glycol dimethyl ether was used as plasticiser to increase the conductivity of the materials. A conductivity of 10-5 S cm-1 was obtained at room temperature for the plasticised polymer samples. Effects of polymer structure, plasticiser, salt concentration and temperature on conductivity and glass transition temperature of the polymer electrolytes are discussed.

AB - Methoxy-ethylene glycol methacrylates, CH2CMeCOO(CH2CH2O)nMe (n = 1, 2, 3), ethoxy-triethylene glycol methacrylate, CH2CMeCOO(CH2CH2O)3Et, and N,N-dimethylaminoethyl methacrylate, CH2CMeCOOCH2CH2NMe2, were used to synthesise the corresponding polymers. Conductivities of these polymers complexed with lithium perchlorate were investigated. Tetraethylene glycol dimethyl ether was used as plasticiser to increase the conductivity of the materials. A conductivity of 10-5 S cm-1 was obtained at room temperature for the plasticised polymer samples. Effects of polymer structure, plasticiser, salt concentration and temperature on conductivity and glass transition temperature of the polymer electrolytes are discussed.

KW - glass transition temperature

KW - ionic conductivity

KW - lithium perchlorate

KW - plasticiser

KW - poly(ethylene glycol methacrylate)

KW - polymer electrolyte

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U2 - 10.1016/0013-4686(95)00182-E

DO - 10.1016/0013-4686(95)00182-E

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AN - SCOPUS:0001162877

SN - 0013-4686

VL - 40

SP - 2301

EP - 2304

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 13-14

ER -

Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes

Abstract

Keywords

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