POLAROGRAPHY OF SOME 1,1-DITHIOLATES AND THEIR MERCURY COMPLEXES IN ACETONE

A. M. Bond; A. T. Casey; J. R. Thackeray

doi:10.1149/1.2403291

POLAROGRAPHY OF SOME 1,1-DITHIOLATES AND THEIR MERCURY COMPLEXES IN ACETONE

A. M. Bond, A. T. Casey, J. R. Thackeray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

Dialkyldithiophosphate and dimethyldithioarsinate anions have been found to interact with the DME in acetone via the processes that are presented. The mercury complexes resulting from these steps have also been investigated polarographically, although many could not be isolated, and the overall mechanism has been compared to those exhibited by other 1,1-dithiolate anions. No reduction steps were observed for any of the dithiolates studied.

Original language	English
Pages (from-to)	1502-1506
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	120
Issue number	11
DOIs	https://doi.org/10.1149/1.2403291
Publication status	Published - 1 Jan 1973

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AB - Dialkyldithiophosphate and dimethyldithioarsinate anions have been found to interact with the DME in acetone via the processes that are presented. The mercury complexes resulting from these steps have also been investigated polarographically, although many could not be isolated, and the overall mechanism has been compared to those exhibited by other 1,1-dithiolate anions. No reduction steps were observed for any of the dithiolates studied.

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POLAROGRAPHY OF SOME 1,1-DITHIOLATES AND THEIR MERCURY COMPLEXES IN ACETONE

Abstract

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